1082207-38-2

Upstream product

• 908078-85-3 (2-(2,2-dibromo-1-methylcyclopropyl)ethyl)benzene 
• 6683-51-8 2-methyl-4-phenyl-1-butene 
• 33501-91-6 (E,Z)-3-methyl-5-phenylpent-2-ene 
• 1082207-57-5 C₁₄H₁₆O₃ 

Downstream Products

• 76803-81-1 2-methyl-2-(2-phenylethyl)but-3-enoic acid 
• 55066-45-0 3-methyl-5-phenylpent-1-en-3-ol 
• 1206588-28-4 (3-(but-3-enyloxy)-3-methylpent-4-enyl)benzene 
• 1206588-26-2 (3-ethoxy-3-methylpent-4-enyl)benzene 
• 1206588-31-9 (3-methyl-3-(neopentyloxy)pent-4-enyl)benzene 
• 1206588-32-0 (E)-(3-(cinnamyloxy)-3-methylpent-4-enyl)benzene 
• 1206588-29-5 (3-methyl-3-phenethoxypent-4-enyl)benzene 
• 1206588-30-8 (3-methyl-3-(2-phenylpropoxy)pent-4-enyl)benzene 
• 1206588-27-3 (3-methyl-3-(4-phenylbutoxy)pent-4-enyl)benzene 
• 1206588-24-0 (4-iodo-3-methyl-3-(4-phenylbutoxy)pent-4-en-1-yl)benzene 
• 1206588-33-1 (3-isopropoxy-3-methylpent-4-enyl)benzene 
• 1431294-95-9 (E)-4,5-dimethyl-1,7-diphenylhept-4-en-3-one 
• 1431294-96-0 (Z)-4,5-dimethyl-1,7-diphenylhept-4-en-3-one 

Relevant academic research and scientific papers

Hydrodehalogenation of Haloarenes by a Sodium Hydride–Iodide Composite

A simple protocol for hydrodebromination and -deiodination of halo(hetero)arenes was enabled by sodium hydride (NaH) in the presence of lithium iodide (LiI). Mechanistic studies showed that an unusual concerted nucleophilic aromatic substitution operates in the present process.

Construction of All-Carbon Chiral Quaternary Centers through CuI-Catalyzed Enantioselective Reductive Hydroxymethylation of 1,1-Disubstituted Allenes with CO2

A catalytic enantioselective construction of all-carbon chiral quaternary centers through reductive hydroxymethylation of 1,1-disubstituted allenes with CO2 has been developed. In the presence of a copper/Mandyphos catalyst, CO2 is t

Hydrocarboxylation of allenes with CO2 catalyzed by silyl pincer-type palladium complex

Tridentate PSiP pincer-type palladium complex-catalyzed hydrocarboxylation of allenes under carbon dioxide to give synthetically useful β,γ-unsaturated carboxylic acids was developed. This novel CO2-fixation reaction is thought to proceed through the catalytic generation of σ-allyl palladium species via hydropalladation of allenes, followed by its regioselective nucleophilic addition to CO2 in the presence of an appropriate reducing agent. The reaction is successfully applied to various allenes bearing functional groups such as ester, carbamate, ketone, and alkene, showing high synthetic utility of this protocol. Copyright