108229-29-4Relevant academic research and scientific papers
1,4-Asymmetric induction in the titanium-mediated aldol reactions of α-benzyloxy methyl ketones
Pellicena, Miquel,Solsona, Joan G.,Romea, Pedro,Urpí, Fèlix
, p. 5265 - 5267 (2008/12/21)
Good levels of 1,4-anti asymmetric induction are obtained in the TiCl3(i-PrO)-mediated aldol reaction of α-benzyloxy methyl ketones with achiral aldehydes. Such methodology represents a new approach to the substrate-controlled acetate aldol reaction, which can be useful to design more efficient synthesis.
Trisubstituted (Stannylmethyl)lithium as a Methylene Double Anion Equivalent. Reaction with Esters
Sato, Tadashi,Matsuoka, Hiroharu,Igarashi, Tsutomu,Minomura, Masafumi,Murayama, Eigoro
, p. 1207 - 1212 (2007/10/02)
Trisubstituted (stannylmethyl)lithium reacts with electrophiles as a methylene double anion equivalent to produce enolates from esters.The reaction mechanism is discussed.
THE REACTION OF α-STANNYLMETHYLLITHIUM WITH ESTERS
Sato, Tadashi,Matsuoka, Hiroharu,Igarashi, Tsutomu,Murayama, Eigoro
, p. 4339 - 4342 (2007/10/02)
Ketonic compounds were prepared from esters using α-stannylmethyllithium as the reagent.
