108250-52-8Relevant articles and documents
Ternary charge transfer complexes. IV. Complexes with Fe, Nb, Ta, Mo, W, or U in the anion
Brownstein, Sydney,Gabe, Eric,Irish, Bridget,Lee, Florence,Louie, Brenda,Piotrowski, Andrej
, p. 445 - 450 (2007/10/02)
NOMX6*aromatic charge transfer complexes are formed from NOX and NbX5 or TaX5, where X may be F or Cl and the aromatic portion is a methyl-substituted benzene.NOMoF6, NOUF6, NOUF7, and NOWCl7*aromatic complexes have been identified but only oxyfluoro species have been isolated when M is Mo, W, or U.NOTaCl6*hexamethylbenzene crystallizes in the trigonal space group P32, with a = 9.822(3), c = 17.469(7) Angstroem.NOFeCl4*hexamethylbenzene*1/2 benzene crystallizes in the orthorombic space group Ccmb, with a = 14.8009(20), b = 15.7683(10), c = 17.3913(14) Angstroem.High conductivity in these complexes appears to depend upon a long N-O bond.