108264-11-5

Upstream product

• 108341-38-4 (+)-(R)_S-p-tolylsulfinyl-3 (1S,2S,3R,4R) bicyclo(2.2.1)heptene-5 carboxylate de methyle-2 
• 91874-30-5 methyl (E)-(R_S)-3-(p-tolylsulfinyl)prop-1-enoate 
• 63268-43-9 (+)-(S)-dimethyl-p-tolylsulfinylmethanephosphonate 

Relevant academic research and scientific papers

Preparation des (+) et (-) endo et (+) et (-) exo bicyclo(2.2.1)heptene-5 carboxylate de methyle a partir de dienophiles chiraux tres reactifs: les Z et E (R)S p-tolylsulfinyl-3 propenoate de methyle

Methyl Z and E (R)S 3-p-tolylsulfinylpropenoate, obtained via reaction of methyl glyoxylate on (+)-(S) dimethyl phosphoryl methyl p-tolyl sulfoxide, reacted under mild conditions with cyclopentadiene.High stereoselectivity and diastereoselectiv