108341-38-4

Basic information

• Product Name: (+)-(R)_S-p-tolylsulfinyl-3 (1S,2S,3R,4R) bicyclo(2.2.1)heptene-5 carboxylate de methyle-2
• Synonyms: (+)-(R)_S-p-tolylsulfinyl-3 (1S,2S,3R,4R) bicyclo(2.2.1)heptene-5 carboxylate de methyle-2
• CAS NO: 108341-38-4
• Molecular Weight: 290.383
• Mol File: 108341-38-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+)-(R)_S-p-tolylsulfinyl-3 (1S,2S,3R,4R) bicyclo(2.2.1)heptene-5 carboxylate de methyle-2(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(R)_S-p-tolylsulfinyl-3 (1S,2S,3R,4R) bicyclo(2.2.1)heptene-5 carboxylate de methyle-2(108341-38-4)
• EPA Substance Registry System: (+)-(R)_S-p-tolylsulfinyl-3 (1S,2S,3R,4R) bicyclo(2.2.1)heptene-5 carboxylate de methyle-2(108341-38-4)

Safety Data

• Hazardous Substances Data: 108341-38-4(Hazardous Substances Data)

Upstream product

• 63268-43-9 (+)-(S)-dimethyl-p-tolylsulfinylmethanephosphonate 
• 542-92-7 cyclopenta-1,3-diene 
• 91874-30-5 methyl (E)-(R_S)-3-(p-tolylsulfinyl)prop-1-enoate 

Downstream Products

• 103-19-5 di(p-tolyl) disulfide 
• 108264-11-5 (1S,2S,3R,4R)-3-(Toluene-4-sulfonyl)-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester 
• 121416-53-3 (+)-p-tolylthio-3 (1S,4R) bicyclo<2.2.1> heptadiene-2,5 carboxylate-2 de methyle 
• 384-26-9 4-fluorotestosterone propionate 

Relevant articles and documents

Preparation des (+) et (-) endo et (+) et (-) exo bicyclo(2.2.1)heptene-5 carboxylate de methyle a partir de dienophiles chiraux tres reactifs: les Z et E (R)S p-tolylsulfinyl-3 propenoate de methyle

Methyl Z and E (R)S 3-p-tolylsulfinylpropenoate, obtained via reaction of methyl glyoxylate on (+)-(S) dimethyl phosphoryl methyl p-tolyl sulfoxide, reacted under mild conditions with cyclopentadiene.High stereoselectivity and diastereoselectiv