108298-46-0

Basic information

• Product Name: 3-Trimethylsilanyloxy-pyran-2-one
• Synonyms: 3-Trimethylsilanyloxy-pyran-2-one
• CAS NO: 108298-46-0
• Molecular Weight: 184.267
• Mol File: 108298-46-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Trimethylsilanyloxy-pyran-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Trimethylsilanyloxy-pyran-2-one(108298-46-0)
• EPA Substance Registry System: 3-Trimethylsilanyloxy-pyran-2-one(108298-46-0)

Safety Data

• Hazardous Substances Data: 108298-46-0(Hazardous Substances Data)

Upstream product

• 496-64-0 3-hydroxy-2-pyrone 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 

Downstream Products

• 108298-54-0 3-Trimethylsilyloxy-dimethyl-phthalate 

Relevant articles and documents

Syntheses of Highly Substituted Benzenes via Diels-Alder Reactions with 2H-Pyran-2-ones

The 2H-pyran-2-ones (α-pyrones) 1 react as dienes in Diels-Alder reactions with acetylene derivatives.The primarely formed cycloadducts immediately aromatize to benzenes by CO2 elimination.Thus, methyl acetylenedicarboxylate (2a) gives dimethyl phthalates 3, and methyl acetylenediphosphonate (2b) gives dimethyl 1,2-phenylenediphosphonates 8.The reactions of 1-(dimethylamino)-1-methoxyethene (9) with 1 regioselectively produce N,N-dimethylanilines 10 and isomeric homophthalate derivatives 12.Naphthoquinones 14 could be generated from 1,4-benzoquinone (13) and 1 in the presence of acetic anhydride and Pd/C.Hydroxy-2H-pyran-2-ones 4 react via their trimethylsilyl ether 6 analogously with 2a to give dimethyl (trimethylsiloxy)phthalates 7 which are easily converted to phenols 5 by acid-catalyzed hydrolysis.