999-97-3Relevant articles and documents
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Wannagat,U. et al.
, p. 373 - 384 (1970)
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The Instability of Ni{N(SiMe3)2}2: A Fifty Year Old Transition Metal Silylamide Mystery
Faust, Michelle,Bryan, Aimee M.,Mansikkam?ki, Akseli,Vasko, Petra,Olmstead, Marilyn M.,Tuononen, Heikki M.,Grandjean, Fernande,Long, Gary J.,Power, Philip P.
, p. 12914 - 12917 (2015)
The characterization of the unstable NiII bis(silylamide) Ni{N(SiMe3)2}2 (1), its THF complex Ni{N(SiMe3)2}2(THF) (2), and the stable bis(pyridine) derivative trans-Ni{N(SiMe3)2}2(py)2 (3), is described. Both 1 and 2 decompose at ca. 25°C to a tetrameric NiI species, [Ni{N(SiMe3)2}]4 (4), also obtainable from LiN(SiMe3)2 and NiCl2(DME). Experimental and computational data indicate that the instability of 1 is likely due to ease of reduction of NiII to NiI and the stabilization of 4 through dispersion forces.
Deoxygenation of primary amides to amines with pinacolborane catalyzed by Ca[N(SiMe3)2]2(THF)2
Gong, Mingliang,Guo, Chenjun,Jiang, Linhong,Luo, Yunjie,Yu, Chong
supporting information, p. 1201 - 1206 (2021/05/29)
Deoxygenative reduction of amides is a challenging but favorable synthetic method of accessing amines. In the presence of a catalytic amount of Ca[N(SiMe3)2]2(THF)2, pinacolborane (HBpin) could efficiently reduce a broad scope of amides, primary amides in particular, into corresponding amines. Functional groups and heteroatoms showed good tolerance in this process of transformation, and a plausible reaction mechanism was proposed.
Preparation method of silazane
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Paragraph 0020-0021, (2020/10/14)
The invention provides a preparation method of silazane. The preparation method comprises the following steps: carrying out a stirring reaction on monochlorosilane, alkali metal amide, a catalyst anda solvent in a reaction container completely; and after the reaction is finished, carrying out reduced pressure distillation to obtain the silazane. Compared with the prior art, the invention providesa new silazane synthesis technology, the process is simple, the yield is as high as 93.0%, and the purity can reach 93.6%.