1083004-84-5Relevant academic research and scientific papers
Formation of vinyl-, vinylhalide-or acyl-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed enantioselective conjugate additions of Si-containing vinylaluminums to β-substituted cyclic enones
May, Tricia L.,Dabrowski, Jennifer A.,Hoveyda, Amir H.
supporting information; experimental part, p. 736 - 739 (2011/04/15)
A catalytic method for enantioselective conjugate addition (ECA) of Si-containing vinylaluminum reagents to β-substituted cyclopentenones and cyclohexenones is described. Reactions are promoted by 1.0-5.0 mol % of a bidentate NHC-Cu complex, which is prep
