1083078-58-3

Basic information

• Product Name: trans-[RuCl₂(1-(4-phenylimino)-1-(phenylhydrazono)propan-2-one)(4,4'-dimethoxy-2,2'-bipyridine)]
• CAS NO: 1083078-58-3
• Molecular Weight: 639.503
• Mol File: 1083078-58-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-[RuCl₂(1-(4-phenylimino)-1-(phenylhydrazono)propan-2-one)(4,4'-dimethoxy-2,2'-bipyridine)](CAS DataBase Reference)
• NIST Chemistry Reference: trans-[RuCl₂(1-(4-phenylimino)-1-(phenylhydrazono)propan-2-one)(4,4'-dimethoxy-2,2'-bipyridine)](1083078-58-3)
• EPA Substance Registry System: trans-[RuCl₂(1-(4-phenylimino)-1-(phenylhydrazono)propan-2-one)(4,4'-dimethoxy-2,2'-bipyridine)](1083078-58-3)

Safety Data

• Hazardous Substances Data: 1083078-58-3(Hazardous Substances Data)

Upstream product

• 14898-67-0 ruthenium(III) chloride trihydrate 
• 17217-57-1 4,4'-Dimethoxy-2,2'-bipyridin 

Relevant articles and documents

Synthesis, structural characterization, and DFT investigation of azoimine-ruthenium complexes containing aromatic-nitrogen ligands

Seven ruthenium(II) complexes continuing substituted diimine ligands and the azoimine ligand (Az: C6H5N{double bond, long}NC(COCH3){double bond, long}NC6H5) are synthesized and characterized. trans-[Ru(II)(Az)(L)Cl2] [L = 2,2′-bipyridine (bpy) 1, 4,4′-dimethyl-2,2′-bipyridine (dmb) 2, 4,4′-dimethoxy-2,2′-bipyridine (dmeb) 3, 4,4′-di-tertbutyl-2,2′-bipyridine (dtb) 4, 1,10-phenanthroline (phen) 5, 5-amino-1,10-phenanthroline (NH2phen) 6, 5-chlorophenanthroline (Clphen) 7, 3,4,7,8-tetramethyl-1,10-phenanthroline (tmphen) 8] are made by the reaction of RuCl3 hydrate and the ligands in the presence of LiCl. These complexes have been characterized by cyclic voltammetry, UV-Vis spectroscopy, electrochemical measurements and X-ray diffraction analysis for 2 and 5. The electrochemical parameters (EL(L)) of the substituted diimine ligands (L) are reported. The absorption spectrum of 5 in acetonitrile has been modeled by time-dependent density functional theory (TD-DFT) using a hybrid functional, B3LYP, as well as the LanL2DZ basis set.