108462-83-5Relevant academic research and scientific papers
A NOVEL PALLADIUM-CATALYZED REARRANGEMENT OF ACETYLENIC KETONES TO FURANS
Sheng, Huaiyu,Lin, Shouyuan,Huang, Yaozeng
, p. 4893 - 4894 (1986)
A novel rearrangement of 1-aryl-4-alkyl-2-butyn-1-one in the presence of Pd(dba)2-PPh3 catalyst gave 2,4-substituted furans in moderate yields.
In site preparation of Pd(II)-MoS2 complex: A new high-efficiency catalyst for alkenylation of heteroaromatics by direct C-H bond activation
Wang, Sheng,Deng, Guoqing,Gu, Jiangjiang,Hua, Wenwen,Jia, Xudong,Xi, Kai
, p. 80 - 85 (2015/11/10)
Pd(II)-MoS2 catalyst was designed by affording Pd2+ salt on the surface of single-layered molybdenum disulfide nanosheets.. Based on the dispersible template, this metal salt and molybdenum disulfide complex offered several advantages, including easy preparation, low cost, and capability to prepare excellent dispersible metal ion cluster nanostructures. The application of this complex in alkenylation of heteroaromatics was reported. Direct C-H activation of indoles, furans and thiophenes was carried out to combine with several kinds of terminal olefins. This catalyst also performed high efficiency in several other kinds of coupling reactions. Thus, a universal suitable catalyst for C-H activation and CC bond formation was invented by a convenient in situ preparation.
