108470-07-1

Upstream product

• 108470-06-0 (2Z,4S,5S,6S)-7-O-benzyloxy-5-hydroxy-2,4,6-trimethylhept-2-enoic acid δ-lactone 
• 67-63-0 isopropyl alcohol 
• 26291-75-8 (R)-1-((3aR,5S,6R,6aR)-2,2,6-trimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethane-1,2-diol 
• 86746-60-3 3,5,6-trideoxy-1,2-O-isopropylidene-3-C-methyl-5-methylene-α-D-ribo-hexafuranose 
• 114144-67-1 6-O-benzyl-3-deoxy-1,2-O-isopropylidene-3-C-methyl-α-D-allofuranose 
• 113660-85-8 3,5-dideoxy-1,2-O-isopropylidene-3,5-di-C-methyl-β-L-talofuranose 
• 108470-05-9 5-O-benzyl-2,4-dideoxy-3-O-formyl-2,4-di-C-methyl-L-lyxose 
• 100-44-7 benzyl chloride 
• 114183-10-7 3,6-dideoxy-1,2-O-isopropylidene-3-C-methyl-α-D-allofuranose 
• 72353-13-0 1-((3aR,5S,6S,6aR)-2,2,6-Trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethanone 
• 56982-95-7 (3aR,5S,6R,6aR)-2,2,6-trimethyl-5-((R)-oxiran-2-yl)tetrahydrofuro[2,3-d][1,3]dioxole 
• 114183-13-0 5-C-(tert-butyldimethylsilyloxy)methyl-3,5-dideoxy-1,2-O-isopropylidene-3-C-methyl-β-L-talofuranose 
• 114244-48-3 6-O-tert-buthyldimethylsilyl-3-deoxy-1,2-O-isopropylidene-3-C-methyl-α-D-allofuranose 
• 114144-71-7 6-O-(tert-butyldimethylsilyl)-3,5-dideoxy-1,2-O-isopropylidene-3-C-methyl-5-C-methylene-α-D-ribo-hexofuranose 

Downstream Products

• 114144-59-1 (2R,3S,4S,6R)-3-(tert-Butyl-dimethyl-silanyloxy)-8-(dimethoxy-phosphoryl)-2,4,6-trimethyl-7-oxo-octanoic acid (S)-2-benzyloxy-1-ethyl-2-methyl-3-oxo-propyl ester 
• 90094-00-1 (2R,3S,4S,6R,8E,10S,11R)-3-tert-butyldimethylsilyloxy-10,11-<(R)-(4-methoxybenzylidene)dioxy>-2,4,6,10-tetramethyl-7-oxo-8-tridecenoic acid 
• 108507-28-4 10-O-benzyl-3-O-tert-butyldimethylsilylmethynolide 
• 108470-11-7 10-O-benzylmethynolide 
• 90074-11-6 (2R,4S,5S,6S)-5-tert-butyldimethylsilyloxy-7-(4-methoxybenzyl)oxy-2,4,6-trimethylheptanal 
• 90074-07-0 (2R,4S,5S,6S)-7-(4-methoxybenzyl)oxy-2,4,6-trimethylheptane-1,5-diol 
• 534-32-7 methynolide 
• 114144-80-8 (2S,3R,5S,6S)-6-<(2S)-1-benzyloxyprop-2-yl>-3,5-dimethyl-2-isopropoxytetrahydropyran 

Relevant academic research and scientific papers

HIGHLY STEREOSELECTIVE SYNTHESIS OF METHYNOLIDE, THE AGLYCONE OF THE 12-MEMBERED RING MACROLIDE METHYMYCIN, FROM D-GLUCOSE

A highly stereoselective and efficient synthesis of methynolide, the aglycone of 12-membered macrolide methymycin, was achieved from of C1-C8 and C9-C13 segments synthesized from D-glucose by employing some stereoselective reactions and benzyl-type protec