1084801-26-2Relevant academic research and scientific papers
Mn(III)-based radical addition reactions of 2-nitroindole with activated CH compounds
Androsov, Dmitry A.,Kishbaugh, Tara L.S.,Gribble, Gordon W.
body text, p. 6621 - 6623 (2009/04/06)
2-Nitroindole undergoes addition reactions with the radicals generated from active CH compounds upon treatment with Mn(OAc)3·2H2O to afford the corresponding 3-substituted-2-nitroindoles in 27-66% yields. Products of the methylene addition reactions undergo a subsequent in situ Nef reaction to afford 2-oxoindolin-3-ylidenes.
