1084895-79-3Relevant academic research and scientific papers
p-Diethynylbenzene-based molecular wires, Fe-C{triple bond, long}C-p-C6H2X2-C{triple bond, long}C-Fe [Fe = Fe(η5-C5Me5)(dppe)]: Synthesis, substituent effects and unexpected formation of be
Matsuura, Yumi,Tanaka, Yuya,Akita, Munetaka
supporting information; experimental part, p. 1840 - 1847 (2009/08/14)
A series of p-diethynylbenzene-based molecular wires, Fe-C{triple bond, long}C-p-C6H2X2-C{triple bond, long}C-Fe (3) (Fe = FeCp*(dppe)), is prepared and their wire-like performance is estimated on the basis of t
Highly luminescent BODIPY-based organoboron polymer exhibiting supramolecular self-assemble structure
Nagai, Atsushi,Miyake, Junpei,Kokado, Kenta,Nagata, Yuuya,Chujo, Yoshiki
supporting information; experimental part, p. 15276 - 15278 (2009/03/12)
A novel class of rod-coil type-organoboron polymers with p-phenylene-ethynylene as the rod segment and long alkyl chain (decyl group) as coil segment has been prepared from a Sonogashira-Hagihara coupling reaction of a BODIPY-based monomer having bis-iodophenyl and decyl groups with diyne monomers, 1,4-diethynylbenzene (a), 1,4-diethynyl-2,5-bis(trifluoromethyl)benzene (b), and 2,7-diethynyl-9,9-dihexyl-9H-fluorene (c). The characterization by means of scanning electron microscopy (SEM) and transmission electron microscopy (TEM) revealed the strong tendency of the obtained polymers, 2a, 2b, and 2c, to self-assemble into particles in solution and as-casted films on a μm-nm scale. Especially, 2a showed the presence of nm-sized particles and μm-sized fiber-like structures formed by aggregation of each particle. Further, in CHCl3, the gelation of 2a by three-dimensional aggregation of each fiber was observed at room temperature after 24 h. Their luminescent properties showed high energy transfer efficiency from π-conjugated polymer linkers to BODIPY moieties (ΦF > 71%). Copyright
