108508-58-3Relevant academic research and scientific papers
SHORT-STEP SYNTHESIS OF 1,3-DIMETHYL-2,9-DIOXABICYCLO NONANE: AN INSECT ATTRACTANT.
Kongkathip, Boonsong,Kongkathip, Ngampong
, p. 2175 - 2176 (1984)
Endo-and exo-1,3-dimethyl-2,9-dioxabicyclo nonane were synthesized in a three-step sequence starting from acetylacetone involving intramolecular cyclization using palladium chloride as catalyst.
Practical one-pot stereospecific preparation of vicinal and 1,3-diols
Bohman, Bjorn,Flematti, Gavin R.,Unelius, C. Rikard
supporting information, p. 75 - 77 (2016/12/23)
A facile one-pot synthesis providing vicinal diols and 1,3-diols in >95% stereoisomeric purity from commercially available enantiopure hydroxy esters has been developed. The esters were reduced with DIBALH and alkylated in situ with 4-pentenylmagnesium br
Enantioselective Synthesis of (+)-endo- and (-)-exo-1,3-Dimethyl-2,9-dioxabicyclononane
Page, Philip C. Bulman,Rayner, Christopher M.,Sutherland, Ian O.
, p. 2403 - 2408 (2007/10/02)
The title compounds, one which is a host-specific substance isolated from the Norway Spruce Picea abies infested by the ambrosia beetle Trypodendron lineatum, have been synthesised in an enantioselective and diastereospecific manner using the Sharpless asymmetric epoxidation as the key step and source of optical activity.
STEREOSPECIFIC SYNTHESIS OF EXO- AND ENDO-1,3-DIMETHYL-2,9-DIOXABICYCLO--NONANE
Page, Philip C. Bulman,Rayner, Christopher M.,Sutherland, Ian O.
, p. 3535 - 3538 (2007/10/02)
The title compounds may be synthesised in an enantioselective and diastereospecific manner from (+/-)-4-hydroxynona-2,8-diene using the Sharpless asymmetric epoxidation as the key step in the reaction sequence.
