1085304-09-1Relevant articles and documents
Stereoselective synthesis of α-glycosyl phosphites and phosphoramidites via o-selective glycosylation of H-phosphonate derivatives
Matsumura, Fumiko,Oka, Natsuhisa,Wada, Takeshi
supporting information; experimental part, p. 5297 - 5300 (2009/06/18)
(Chemical Equation Presented) A highly stereo- and chemoselective glycosylation of H-phosphonate derivatives with glycosyl iodides was discovered as a reverse reaction of the formation of a glycosyl iodide from a glycosyl phosphite and I- under mild acidic conditions. Further study on the unique reaction showed that the reaction provided various α-glycosyl phosphites and phosphoramidites In a highly stereoselective manner with complete O-selectivity.