108613-01-0Relevant articles and documents
Me3SiCl/HMPA ACCELERATED CONJUGATE ADDITION OF CATALYTIC COPPER REAGENT. STEREOSELECTIVE SYNTHESIS OF ENOL SILYL ETHER OF ALDEHYDE
Horiguchi, Yoshiaki,Matsuzawa, Satoshi,Nakamura, Eiichi,Kuwajima, Isao
, p. 4025 - 4028 (1986)
Copper-catalyzed conjugate addition of Grignard reagents in the presence of Me3SiCl and HMPA proceeds in much higher yield than the reaction of conventional organocopper reagents and shows very good regio-, stereo-, and chemoselectivities.