108613-06-5

Basic information

• Product Name: N-(4-bromophenyl)-1-tert-butyl-1,1-dimethylsilanamine
• Synonyms: N-(4-bromophenyl)-1-tert-butyl-1,1-dimethylsilanamine
• CAS NO: 108613-06-5
• Molecular Weight: 286.287
• Mol File: 108613-06-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-(4-bromophenyl)-1-tert-butyl-1,1-dimethylsilanamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-bromophenyl)-1-tert-butyl-1,1-dimethylsilanamine(108613-06-5)
• EPA Substance Registry System: N-(4-bromophenyl)-1-tert-butyl-1,1-dimethylsilanamine(108613-06-5)

Safety Data

• Hazardous Substances Data: 108613-06-5(Hazardous Substances Data)

Upstream product

• 108613-05-4 t-butyldimethylsilyl trichloroacetate 
• 106-40-1 4-bromo-aniline 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 106-40-1 4-bromo-aniline 

Relevant articles and documents

Highly efficient chemoselective N-TBS protection of anilines under exceptional mild conditions in the eco-friendly solvent 2-methyltetrahydrofuran

A straightforward chemoselective protection of anilines as N-TBS derivatives is described by using a suitable deprotonation of the amine with methyllithium in the environmentally friendly and safer substitute of THF, 2-methyltetrahydrofuran, under exceptional mild reaction conditions (0 °C, 30 min). Interestingly, the protecting group maybe cleaved efficiently by simple treatment of N-TBS-anilines with silica gel in ethanol-water.