108641-69-6Relevant academic research and scientific papers
EQUILIBRIA INVOLVING HEMIKETAL AND KETAL FORMATION FROM 2-HALOGENOACETOPHENONES
Toeke, Laszlo,Keglevich, Gyoergy,Petnehazy, Imre,Szoelloesy, Aron
, p. 103 - 110 (2007/10/02)
1H-, 13C-NMR, GC measurements and some preparative work have been made to determine the hemiketal and ketal concentrations in mixtures of alcohols and 2-halogenoacetophenones.Equilibrium values for these products, as well as the time required to reach the equilibrium in the absence of acid, were found to be surprisingly high.Comparisons of the values with those of chloroacetone have also been accomplished.
