1086529-40-9Relevant academic research and scientific papers
Metal-free catalytic hydrogenation of enamines, imines, and conjugated phosphinoalkenylboranes
Spies, Patrick,Schwendemann, Sina,Lange, Stefanie,Kehr, Gerald,Froehlich, Roland,Erker, Gerhard
, p. 7543 - 7546 (2008)
(Chemical Equation Presented) The metal-free hydrogen activator 1 catalyzes the unique P/B hydrogenation of the frustrated Lewis pair 3, which itself is inactive toward H2 under the applied conditions, to yield the hydrogenation product 4. System 1/2 (5 mol%) also catalyzes the hydrogenation of a bulky ketimine and of enamines under mild conditions (2.5 bar H2, RT) to yield the respective amines.
