108656-63-9Relevant academic research and scientific papers
Medium-Sized Cyclophanes, 20. Synthesis and Conformational Studies of syn- and anti-Dihydroxymetacyclophanes
Yamato, Takehiko,Matsumoto, Jun-ichi,Tokuhisa, Kiwamu,Kajihara, Masami,Suehiro, Kazuaki,Tashiro, Masashi
, p. 2443 - 2454 (2007/10/02)
syn- and anti-Dimethoxymetacyclophanes 9 are obtained by pyrolysis of the corresponding anti-sulfones 8, which are prepared by the reaction of 1,n-bisalkanes 6 with Na2S in ethanol under the high dilution conditions,
Preparation and Conformational Properties of Tetrahydroxymetacyclophanes
Yamato, Takehiko,Saruwatari, Yoshiyuki,Nagayama, Souichiro,Maeda, Kenji,Tashiro, Masashi
, p. 861 - 862 (2007/10/02)
The preparation of a novel macrocyclic compound, tetrahydroxymetacyclophane 5 by base-catalysed condensation of 1,3-(2,2'-dihydroxy-5,5'-di-tert-butyldiphenyl)propane 4 with formaldehyde in xylene in 90percent yield is described and its conformat
