Cas 1086602-82-5,Mo(P(CH3)3)4H3(SC6H4CH2CH3)

1086602-82-5

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Product Name: Mo(P(CH₃)3)4H₃(SC₆H₄CH₂CH₃)
Synonyms:
CAS NO:1086602-82-5
Molecular Formula:
Molecular Weight: 540.502
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: Mo(P(CH₃)3)4H₃(SC₆H₄CH₂CH₃)(CAS DataBase Reference)
NIST Chemistry Reference: Mo(P(CH₃)3)4H₃(SC₆H₄CH₂CH₃)(1086602-82-5)
EPA Substance Registry System: Mo(P(CH₃)3)4H₃(SC₆H₄CH₂CH₃)(1086602-82-5)

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Hazardous Substances Data: 1086602-82-5(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 1086602-82-5 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,8,6,6,0 and 2 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 1086602-82:
(9*1)+(8*0)+(7*8)+(6*6)+(5*6)+(4*0)+(3*2)+(2*8)+(1*2)=155
155 % 10 = 5
So 1086602-82-5 is a valid CAS Registry Number.

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1086602-82-5Relevant academic research and scientific papers

Reactivity of Mo(PMe3)6 towards benzothiophene and selenophenes: New pathways relevant to hydrodesulfurization

Buccella, Daniela,Janak, Kevin E.,Parkin, Gerard

, p. 16187 - 16189 (2008)

Mo(PMe3)6 cleaves a C-S bond of benzothiophene to give (κ2-CHCHC6H4S)Mo(PMe3)4, which rapidly isomerizes to the olefin-thiophenolate and 1-metallacyclopropene-thiophenolate complexes, (κ1,η2-CH2CHC6H4S)Mo(PMe3)3(η2-CH2PMe2) and (κ1,η2-CH2CC6H4S)Mo(PMe3)4. The latter two molecules result from a series of hydrogen transfers and are differentiated according to whether the termini of the organic fragments coordinate as olefin or η2-vinyl ligands, respectively. The reactions between Mo(PMe3)6 and selenophenes proceed differently from those of the corresponding thiophenes. For example, whereas Mo(PMe3)6 reacts with thiophene to give η5-thiophene and butadiene-thiolate complexes, (η5-C4H4S)Mo(PMe3)3 and (η5-C4H5S)Mo(PMe3)2(η2-CH2PMe2), selenophene affords the metallacyclopentadiene complex [(κ2-C4H4)Mo(PMe3)3(Se)]2[Mo(PMe3)4] in which the selenium has been completely abstracted from the selenophene moiety. Likewise, in addition to (κ1,η2-CH2CC6H4Se)Mo(PMe3)4 and (κ1,η2-CH2CHC6H4Se)Mo(PMe3)3(η2-CH2PMe2), which are counterparts of the species observed in the benzothiophene reaction, the reaction of Mo(PMe3)6 with benzoselenophene yields products resulting from C-C coupling, namely [κ2,η4-Se(C6H4)(CH)4(C6H4)Se]Mo(PMe3)2 and [μ-Se(C6H4)(CH)C(CH)2(C6H4)](μ-Se)[Mo(PMe3)2][Mo(PMe3)2H]. Copyright

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