108662-09-5

Basic information

• Product Name: (Z)-5-(1',3'-dioxan-2'-yl)-1-(phenylsulfonyl)pent-1-en-3-one
• Synonyms: (Z)-5-(1',3'-dioxan-2'-yl)-1-(phenylsulfonyl)pent-1-en-3-one
• CAS NO: 108662-09-5
• Molecular Weight: 310.371
• Mol File: 108662-09-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (Z)-5-(1',3'-dioxan-2'-yl)-1-(phenylsulfonyl)pent-1-en-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-5-(1',3'-dioxan-2'-yl)-1-(phenylsulfonyl)pent-1-en-3-one(108662-09-5)
• EPA Substance Registry System: (Z)-5-(1',3'-dioxan-2'-yl)-1-(phenylsulfonyl)pent-1-en-3-one(108662-09-5)

Safety Data

• Hazardous Substances Data: 108662-09-5(Hazardous Substances Data)

Upstream product

• 33884-43-4 2-(2-Bromoethyl)-1,3-dioxane 
• 108643-96-5 5-(1',3'-dioxan-2'-yl)-1-(phenylthio)pentan-3-one 
• 108-98-5 thiophenol 
• 51849-21-9 β-(phenylthio)propionyl chloride 
• 5219-65-8 acide phenylthio-3 propanoique 
• 22198-59-0 methyl 3-phenylthiopropanoate 
• 108662-08-4 (Z)-5-(1',3'-dioxan-2'-yl)-1-(phenylthio)pent-1-en-3-one 

Downstream Products

• 122334-28-5 (1R,3aS,4R,7aR)-4-[1,3]Dioxan-2-ylmethyl-1-[(R)-3-(diphenyl-phosphinoyl)-1-methyl-propyl]-7a-methyl-octahydro-inden-5-one 
• 122334-27-4 (1RS,1'RS,3aSR,4SR,7aRS)-4-<(1''',3'''-dioxan-2'''-yl)methyl>-1-<3'-(diphenylphosphinoyl)-1'-methylpropyl>-7a-methyloctahydro-5H-inden-5-one 
• 122406-57-9 (1R,3aR,7aR)-4-[1,3]Dioxan-2-ylmethyl-1-[(R)-3-(diphenyl-phosphinoyl)-1-methyl-propyl]-7a-methyl-octahydro-inden-5-one 
• 122334-29-6 (1RS,1'RS,3aSR,4SR,7aRS)-4-<(1''',3'''-dioxan-2'''-yl)methyl>-1-<3'-(diphenylphosphinoyl)-1'-methylpropyl>-7a-methyloctahydro-1H-inden-5-ol 
• 122334-29-6 (1RS,1'RS,3aSR,4SR,7aRS)-4-<(1''',3'''-dioxan-2'''-yl)methyl>-1-<3'-(diphenylphosphinoyl)-1'-methylpropyl>-7a-methyloctahydro-1H-inden-5-ol 
• 122334-20-7 (2RS,2'RS,3RS)-2-<5''-(1''',3'''-dioxan-2'''-yl)-3''-oxopentyl>-3-<3'-(diphenylphosphinoyl)-1'-methylpropyl>-2-methylcyclopentanone 
• 122334-21-8 (1RS,1'RS,7aRS)-4-<(1''',3'''-dioxan-2'''-yl)methyl>-1-<3'-(diphenylphosphinoyl)-1'-methylpropyl>-7a-methyl-1,2,3,6,7,7a-hexahydro-5H-inden-5-one 
• 122334-23-0 (1RS,1'RS,5SR,7aRS)-4-<(1''',3'''-dioxan-2'''-yl)methyl>-1-<3'-(diphenylphosphinoyl)-1'-methylpropyl>-7a-methyl-2,3,5,6,7,7a-hexahydro-1H-inden-5-ol 
• 122334-25-2 (1RS,1'RS,7aRS)-4-<(1''',3'''-dioxan-2'''-yl)methyl>-1-<3'-(diphenylphosphinoyl)-1'-methylpropyl>-7a-methyl-2,6,7,7a-tetrahydro-1H-indene 
• 122406-52-4 (1'RS,1''Z,2SR,2'E,3SR)-2-<5''-(1''',3'''-dioxan-2'''-yl)-3''-oxopent-1''-enyl>-3-<3'-(diphenylphosphinoyl)-1'-methylprop-2'-enyl>-2-methylcyclopentanone 
• 122406-51-3 (1'RS,1''E,2SR,2'E,3SR)-2-<5''-(1''',3'''-dioxan-2'''-yl)-3''-oxopent-1''-enyl>-3-<3'-(diphenylphosphinoyl)-1'-methylprop-2'-enyl>-2-methylcyclopentanone 

Relevant articles and documents

The Preparation of Some β-Sulfonylacrylate Thioesters and β-Sulfonylvinyl Ketones

β-Sulfonylacrylate phenyl and t-butyl thioesters, and β-sulfonylvinyl ketones have been prepared by oxidation of the corresponding β-aryl- and β-alkyl-thio compounds.In one case the β-sulfonylvinyl ketone was obtained from an epoxy sulfone.The β-aryl- and β-alkyl-thio compounds were obtained by chlorination-dehydrochlorination of saturated precursors.The reactions of 3-(phenylthio)propionyl chloride with organocadmium and Grignard reagents were used to prepare some of the saturated precursors of the β-sulfonylvinyl ketones.