108665-44-7Relevant articles and documents
A novel approach to C-trimethylsilyl-1,3-azoles
Zarudnitskii, Evgenij V.,Pervak, Igor I.,Merkulov, Anatolij S.,Yurchenko, Aleksandr A.,Tolmachev, Andrej A.,Pinchuk, Aleksandr M.
, p. 1279 - 1282 (2007/10/03)
Direct silylation of 1,3-azoles with bromotrimethylsilane in the presence of triethylamine was investigated. 5-Phenyloxazole, benzoxazole, 1-methyl-1,2,4-triazole, 2-aryl-1,3,4-oxa- and thiadiazoles were found to give the corresponding 2- or 5-trimethylsi
Synthesis and Carbodemetalation Reactions of 4-Methyl- and 5-Aryl-2-(trimethylsilyl)oxazoles. C-C Bond Formation at C2 of the Oxazole Ring
Dondoni, Alessandro,Fantin, Giancarlo,Fogagnolo, Marco,Medici, Alessandro,Pedrini, Paola
, p. 3413 - 3420 (2007/10/02)
The title compounds 6a-d have been prepared by sequential lithiation and silylation of the corresponding 2-H oxazoles and isomerization of the resulting α-isocyano silyl enol ethers.Silyloxazoles 6a-d behave as stable 2-oxazolyl anion equivalents toward v
