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108695-63-2

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108695-63-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 108695-63-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,8,6,9 and 5 respectively; the second part has 2 digits, 6 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 108695-63:
(8*1)+(7*0)+(6*8)+(5*6)+(4*9)+(3*5)+(2*6)+(1*3)=152
152 % 10 = 2
So 108695-63-2 is a valid CAS Registry Number.

108695-63-2Relevant articles and documents

Synthesis of unsymmetrical 3,4-diaryl-3-pyrrolin-2-ones utilizing pyrrole weinreb amides

Greger, Jessica G.,Yoon-Miller, Sarah J. P.,Bechtold, Nathan R.,Flewelling, Scott A.,MacDonald, Jacob P.,Downey, Catherine R.,Cohen, Eric A.,Pelkey, Erin T.

, p. 8203 - 8214 (2011/12/04)

A regiocontrolled synthesis of unsymmetrical 3,4-diaryl-3-pyrrolin-2-ones has been achieved in three steps from 1,2-diaryl-1-nitroethenes with pyrrole-2-carboxamides (pyrrole Weinreb amides) serving as the key linchpin intermediates. Two different methods for the preparation of the requisite nitroalkenes were investigated: (1) modified Henry reaction between arylnitromethanes and arylimines; and (2) Suzuki-Miyaura cross-coupling reaction of 2-aryl-1-bromo-1-nitroethenes with arylboronic acids. Some difficulty was encountered in the preparation of arylnitromethanes, thus leading to the exploration of a cross-coupling strategy that proved more useful. A Barton-Zard pyrrole cyclocondensation reaction between 1,2-diaryl-1-nitroethenes and N-methoxy-N-methyl-2-isocyanoacetamide gave the corresponding pyrrole Weinreb amides, which were then converted into the desired 3-pyrrolin-2-ones in two steps. Overall, this method allowed for the construction of 3,4-diaryl-3- pyrrolin-2-ones with complete regiocontrol of the substituents with respect to the lactam carbonyl. The utility of this synthetic methodology was demonstrated by the preparation of eight unsymmetrical and symmetrical 3,4-diaryl-3-pyrrolin- 2-ones including the N-H lactam analogue of the selective COX-II inhibitor, rofecoxib.

High Intrinsic Rate Constant and Large Imbalances in the Thiolate Ion Addition to Substituted α-Nitrostilbenes

Bernasconi, Claude F.,Killion, Robert B.

, p. 7506 - 7512 (2007/10/02)

The kinetics of the reversible addition of alkyl thiolate ions (RS- with R = Et, HOCH2CH2, CH3OCOCH2CH2, and CH3OCOCH2) to α-nitrostilbene and of HOCH2CH2S- to α-nitrostilbene substituted in the α-phenyl ring (Z = 4-CH3, H, 4-Br, 3-N

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