1086975-14-5Relevant academic research and scientific papers
Copper-catalyzed trifluoromethylthiolation of primary and secondary alkylboronic acids
Shao, Xinxin,Liu, Tianfei,Lu, Long,Shen, Qilong
supporting information, p. 4738 - 4741 (2015/04/27)
A Cu-catalyzed trifluoromethylthiolation of primary and secondary alkylboronic acids with an electrophilic trifluoromethylthiolating reagent is described. Tolerance for a variety of functional groups was observed.
Utilization of potassium vinyltrifluoroborate in the development of a 1,2-dianion equivalent
Molander, Gary A.,Sandrock, Deidre L.
supporting information; experimental part, p. 2369 - 2372 (2009/11/30)
Previous studies of orthogonally reactive dibora species led to the discovery of a unique reactivity pattern associated with potassium vinyltrifluoroborate. Upon hydroboration, the vinyltrifluoroborate generates a 1,2-diboraethane, which is distinct from
Orthogonal reactivity in boryl-substituted organotrifluoroborates
Molander, Gary A.,Sandrock, Deidre L.
, p. 15792 - 15793 (2009/05/15)
A method was developed for the hydroboration of alkenyl-containing organotrifluoroborates to generate dibora intermediates. The reactivity differences between organotrifluoroborates and trialkylboranes facilitated the cross-coupling of the borane moiety o
