108771-00-2Relevant academic research and scientific papers
PREPARATION OF PYRIDYL GRIGNARD REAGENTS AND CROSS COUPLING REACTIONS WITH SULFOXIDES BEARING AZAHETEROCYCLES
Furukawa, Naomichi,Shibutani, Tadao,Fujihara, Hisashi
, p. 5845 - 5848 (2007/10/02)
Pyridyl Grignard reagents were prepared from the corresponding iodopyridine and EtMgBr.New cross coupling reactions of the Grignard reagents with azaheterocycles took place on the sulfinyl sulfur atom to afford biazaheteroaryls.
REACTIONS OF PYRIDYL AND QUINOLYL SULFOXIDES WITH GRIGNARD REAGENT : A CONVENIENT PREPARATION OF PYRIDYL AND QUINOLYL GRIGNARD REAGENTS
Furukawa, Naomichi,Shibutani, Tadao,Matsumura, Kazunori,Fujihara, Hisashi,Oae, Shigeru
, p. 3899 - 3902 (2007/10/02)
3-,4-Pyridyl and 4-quinolyl Grignard reagents were generated by the reaction of the corresponding phenyl sulfoxides with PhMgBr and give the adducts upon treatment with various aldehydes and ketones.The stereochemistry for the reaction was investigated.
