108794-07-6

Basic information

• Product Name: (-)-8-phenylmenthyl (2S)-2-hydroxy-3-(4-t-butyl-1-cyclohexenyl)propionate
• CAS NO: 108794-07-6
• Molecular Weight: 440.667
• Mol File: 108794-07-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (-)-8-phenylmenthyl (2S)-2-hydroxy-3-(4-t-butyl-1-cyclohexenyl)propionate(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-8-phenylmenthyl (2S)-2-hydroxy-3-(4-t-butyl-1-cyclohexenyl)propionate(108794-07-6)
• EPA Substance Registry System: (-)-8-phenylmenthyl (2S)-2-hydroxy-3-(4-t-butyl-1-cyclohexenyl)propionate(108794-07-6)

Safety Data

• Hazardous Substances Data: 108794-07-6(Hazardous Substances Data)

Upstream product

• 72526-00-2 (-)-8-phenylmenthyl acrylate 
• 104197-95-7 (1R,2S,5R)-2-(1-methyl-1-phenylethyl)-5-methylcyclohexyl nitrooxyacetate 
• 80595-59-1 bromoacetic acid (-)-8-phenylmenthol ester 
• 65253-04-5 (-)-8-phenylmenthol 
• 13294-73-0 1-tert-butyl-4-methylenecyclohexane 
• 84312-20-9 (1R,3R,4S)-8-phenylmenthyl glyoxylate 

Relevant articles and documents

ASYMMETRIC INDUCTION IN THE ENE REACTION OF GLYOXYLATE ESTERS OF 8-PHENYLMENTHOL

We recently communicated (J.K.Whitesell, A.Bhattacharya, D.A.Aguilar and K.Henke, J.Chem.Soc.Chem.Commun. 989 (1982)) a highly efficient and effective method for the control of absolute stereochemistry through asymmetric induction in the ene reaction the chiral glyoxylate 1 with alkenes.We now have accumulated sufficient information on this process in terms of both its mechanistic details as well as its scope and applicability to a variety of situations that warrants a more complete presentation of these reactions.