108802-23-9Relevant academic research and scientific papers
A NEW PYRIDINE SYNTHESIS STARTING FROM α, β-UNSATURATED CARBONYL COMPOUNDS
Konno, Katsuhiro,Hashimoto, Kimiko,Shirahama, Haruhisa,Matsumoto, Takeshi
, p. 3865 - 3868 (2007/10/02)
A new and mild synthetic method of substituted pyridines from α, β-unsaturated carbonyl compounds through a sequence involving (1) 1, 4-conjugate addition of thiophenol (2) condensation with a methylene ketone (3) Pummerer rearrangement to an unsaturated 1, 5-dicarbonyl compound (4) treatment with ammonia is described.
