108867-01-2

Upstream product

• 108866-98-4 (1S,2R,3S,4R,5R)-2,3-Diacetoxy-4,5-dibromo-cyclohexanecarboxylic acid 
• 69982-67-8 DL-2-exo-bromo-4,8-dioxatricyclo<4.2.1.0^3,7>nonan-5-one 
• 104748-84-7 DL-(1,3,5/2,4)-2,3-diacetoxy-4,5-dibromocyclohexane-1-carboxylic acid 

Downstream Products

• 142864-32-2 (1S,2R,3R,5R,8R,10S)-2-benzyloxy-5-phenyl-4,6,11-trioxatricyclo<8.1.0^3.8>undecane 
• 142789-96-6 1,2-O-anhydro-3-O-benzyl-4,6-O-benzylidene-5a-carba-β-D-mannopyranose 
• 142789-89-7 (1R,3R,6R,10S)-10-hydroxy-3-phenyl-2,4-dioxabicyclo<4.4.0>dec-8-ene 
• 142789-92-2 4-O-acetyl-3,6-di-O-benzyl-5a-carba-1,2-di-O-(methylsulfonyl)-α-D-glucopyranose 
• 142789-94-4 N-acetyl-4-O-acetyl-3,6-di-O-benzyl-5a-carba-2-O-(methylsulfonyl)-β-D-glucopyranosylamine 
• 142789-95-5 N-acetyl-2,4-di-O-acetyl-3,6-di-O-benzyl-5a-carba-β-D-mannopyranosylamine 
• 142790-00-9 2-acetamido-1-azido-3-O-benzyl-4,6-O-benzylidene-5a-carba-1,2-dideoxy-Β-D-glucopyranose 
• 142789-97-7 1-azido-3-O-benzyl-4,6-O-benzylidene-5a-carba-1-deoxy-α-D-mannopyranose 
• 142789-91-1 6-O-acetyl-1,5-anhydro-3,4-di-O-benzyl-2-deoxy-5a-carba-D-arabino-hex-1-enitol 
• 142789-90-0 (1R,3R,6R,10S)-10-benzyloxy-3-phenyl-2,4-dioxabicyclo<4.4.0>dec-8-ene 
• 135735-94-3 (1S,2S,3R,4R,5R)-4-O-Acetyl-3-O-benzyl-5-benzyloxymethyl-cyclohexan-1,2,3,4-tetraol 
• 135735-93-2 4-O-acetyl-1,5-anhydro-3,6-di-O-benzyl-2-deoxy-5a-carba-D-arabino-hex-1-enitol 
• 143058-81-5 (1R)-(1,3/2)-3-hydroxymethyl-5-cyclohexene-1,2-diol 
• 131063-67-7 <(1S)-(1,2,4/3,5)-2-Amino-3,4-dihydroxy-5-hydroxymethyl-1-cyclohexyl> β-D-glucopyranoside 

Relevant academic research and scientific papers

Pseudo-Sugars. XVI. Facile Synthesis of Pseudo -α-D and L-Glucopyranoses

Optically active pseudo-α-glucopyranoses have been synthesized from enantiomeric (1,3,5/2,4)-2,3-diacetoxy-4,5-dibromo-1-cyclohexanecarboxylic acids, obtained by optical resolution of the racemic modification using (+)- and (-)-α-methylbenzylamines.

SYNTHESIS OF METHYL DL-(1,3/2,4,5)- AND DL-(1,3,4/2,5)-2,3,4,5-TETRAHYDROXYCYCLOHEXANE-1-CARBOXYLATES

Two new diastereoisomers of the pseudo-hexuronate methyl 2,3,4,5-tetrahydroxycyclohexane-1-carboxylate, having (1,3/2,4,5)- (8) and (1,3,4/2,5)-configurations (16), have been synthesized from the readily available bromo-lactone (1) of the endo-adduct of f