108881-14-7Relevant articles and documents
Thermally Induced Gas Phase Phosphonylation of Arenes via Intramolecular Trapping of an Aryl Metaphosphate Moiety
Cadogan, J. I. G.,Cowley, Alan H.,Gosney, Ian,Pakulski, Marek,Wright, Peter M.,Yaslak, Salih
, p. 1685 - 1686 (2007/10/02)
2-Aryloxy-1,3,2-dioxaphospholanes break down on pyrolysis in the gas phase by a mechanism best accounted for in terms of the formation of metaphosphate (ArOPO2) moieties, which rearrange to cyclic phosphonic monoesters via intramolecular insertion reactions, unless an abstractable β-hydrogen is present when a Chugaev-type reaction takes place to give a terminal alkene.