108921-73-9Relevant articles and documents
Crystal disordering and organic solid-state reactions
Varga, Katarina,Volari, Jana,Vanik, Hrvoj
, p. 1434 - 1438 (2015/02/19)
This work is the extension of our preliminary communication about the relationship between the change in the solid-state structure and the chemical reaction in a crystal. The investigation is a case study about the nature of the adiabatic organic solid-st
Nitrosobenzene cross-dimerization: Structural selectivity in solution and in solid state
Biljan, Ivana,Cvjetojevic, Gorana,Smrecki, Vilko,Novak, Predrag,Mali, Gregor,Plavec, Janez,Babic, Darko,Mihalic, Zlatko,Vancik, Hrvoj
experimental part, p. 22 - 26 (2010/09/16)
Possibility of nitrosobenzenes to form dimeric molecular structures (azodioxides) is used as a model for intermolecular selectivity investigations in solution as well as in solid state. Cross-dimerization of different combinations of p- and m-substituted nitrosobenzene pairs was studied by variable temperature 1H NMR, solid-state NMR (CP MAS), IR, and ab initio calculations. It is evident that p-nitronitrosobenzene behaves nonselectively because it forms dimers with all the studied nitrosobenzene partners. In contrast, p-methoxynitrosobenzene in most cases does not form dimers. The evidence that ability to form dimers is different in solution than in the solid state can be explained by influence of molecular arrangements in the crystal lattice.