108969-87-5

Upstream product

• 2130-96-3 O-benzyl-N-tert-butoxycarbonyl-L-tyrosine 
• 537-49-5 N-methyl-L-tyrosine 
• 67-56-1 methanol 

Downstream Products

• 108969-78-4 methyl N-Cbz-3,5-dichloro-N-methyl-L-tyrosyl-3,5-dibromo-N-methyl-L-tyrosinate 
• 108969-77-3 methyl N-Cbz-3,5-dibromo-N-methyl-L-tyrosyl-3,5-dibromo-N-methyl-L-tyrosinate 
• 178208-39-4 (S)-2-{[(R)-2-(Benzyloxycarbonyl-methyl-amino)-3-(4-hydroxy-phenyl)-propionyl]-methyl-amino}-3-(3,5-dibromo-4-hydroxy-phenyl)-propionic acid methyl ester 
• 1026424-02-1 (S)-2-{[(R)-2-tert-Butoxycarbonylamino-2-(3,5-dichloro-4-hydroxy-phenyl)-acetyl]-methyl-amino}-3-(3,5-dibromo-4-hydroxy-phenyl)-propionic acid methyl ester 
• 246512-34-5 (S)-2-{[(R)-2-[(R)-2-tert-Butoxycarbonylamino-2-(4-hydroxy-3,5-diiodo-phenyl)-acetylamino]-2-(3,5-dichloro-4-hydroxy-phenyl)-acetyl]-methyl-amino}-3-(3,5-dibromo-4-hydroxy-phenyl)-propionic acid methyl ester 
• 246512-35-6 (S)-2-{[(R)-2-[(R)-2-Benzyloxycarbonylamino-2-(4-hydroxy-3,5-diiodo-phenyl)-acetylamino]-2-(3,5-dichloro-4-hydroxy-phenyl)-acetyl]-methyl-amino}-3-(3,5-dibromo-4-hydroxy-phenyl)-propionic acid methyl ester 
• 178357-82-9 (9S,12R)-12-(Benzyloxycarbonyl-methyl-amino)-5-bromo-16,17-dichloro-4-hydroxy-10-methyl-11-oxo-2-oxa-10-aza-tricyclo[12.2.2.1^3,7]nonadeca-1⁽¹⁷⁾,3⁽¹⁹⁾,4,6,14⁽¹⁸⁾,15-hexaene-9-carboxylic acid methyl ester 
• 178208-40-7 (S)-2-{[(R)-2-(Benzyloxycarbonyl-methyl-amino)-3-(3,5-dichloro-4-hydroxy-phenyl)-propionyl]-methyl-amino}-3-(3,5-dibromo-4-hydroxy-phenyl)-propionic acid methyl ester 
• 64725-24-2 deoxybouvadin 
• 122621-60-7 RA-VII 
• 109011-07-6 C₄₁H₅₂N₆O₁₀ 
• 108969-74-0 (9S,12S)-12-(Benzyloxycarbonyl-methyl-amino)-5-bromo-16,17-dichloro-4-hydroxy-10-methyl-11-oxo-2-oxa-10-aza-tricyclo[12.2.2.1^3,7]nonadeca-1⁽¹⁷⁾,3⁽¹⁹⁾,4,6,14⁽¹⁸⁾,15-hexaene-9-carboxylic acid methyl ester 
• 108969-75-1 (9S,12S)-12-(Benzyloxycarbonyl-methyl-amino)-5-bromo-16,17-dichloro-4-methoxy-10-methyl-11-oxo-2-oxa-10-aza-tricyclo[12.2.2.1^3,7]nonadeca-1⁽¹⁷⁾,3⁽¹⁹⁾,4,6,14⁽¹⁸⁾,15-hexaene-9-carboxylic acid methyl ester 
• 108969-84-2 (9S,12S)-9-(Benzyloxycarbonyl-methyl-amino)-5,16,17-tribromo-7-methoxy-11-methyl-4,10-dioxo-2-oxa-11-aza-tricyclo[12.2.2.1^3,7]nonadeca-1⁽¹⁷⁾,3⁽¹⁹⁾,5,14⁽¹⁸⁾,15-pentaene-12-carboxylic acid methyl ester 

Relevant academic research and scientific papers

Macrocyclization by TTN Oxidation for the Synthesis of Chloropeptin Left-Hand Segment

Cyclic tripeptide containing a diphenylether bond of the Chloropeptin left-hand segment were synthesized with the use of TTN phenolic oxidation in high yield. They were found to exist as equilibrium mixtures of two stable conformers caused by a rotation o

Regioselective synthesis of 14-membered biaryl ethers: Total synthesis of RA-VII and deoxybouvardin

In order to obtain a key compound (22a'') for synthesis of RA-VII (1) and deoxybouvardin (2), construction of the 14-membered ring system was performed by means of thallium trinitrate-mediated oxidation of the tetrahalogeno amides 5-7. The dibromo dichlor