108970-88-3

Upstream product

• 75-44-5 phosgene 
• 447463-65-2 1,2,4,5-tetrakis(tert-butylthio)benzene 

Downstream Products

• 1037632-72-6 [Ni(1,2-bis(dicyclohexylphosphino)ethane)(S₂C₆H₂S₂CO)] 
• 1037632-74-8 [(Ni(1,2-bis(dicyclohexylphosphino)ethane))2(1,2,4,5-benzenetetrathiolate)] 
• 1195984-75-8 [Ni(1,2-bis(diphenylphosphino)ethylene)(S₂C₆H₂S₂CO)] 
• 1195984-73-6 [Ni(1,2-bis(diphenylphosphino)ethane)(S₂C₆H₂S₂CO)] 
• 1195984-77-0 [Ni(1,2-bis(diphenylphosphino)benzene)(S₂C₆H₂S₂CO)] 
• 1195984-81-6 [Pd(1,2-bis(dicyclohexylphosphino)ethane)(S₂C₆H₂S₂CO)] 
• 1195984-83-8 [(Ni(1,2-bis(diphenylphosphino)ethane))2(1,2,4,5-benzenetetrathiolate)] 
• 1037632-76-0 [(1,2-bis(dicyclohexylphosphino)ethane)Ni(1,2,4,5-benzenetetrathiolate)Pd(1,2-bis(dicyclohexylphosphino)ethane)] 

Relevant academic research and scientific papers

Fluorescent Dyes with Large Stokes Shifts Based on Benzo[1,2-d:4,5-d']bis([1,3]dithiole) (“S4-DBD Dyes”)

We report on a further development of [1,3]-dioxolo[4.5-f]benzodioxole (DBD) fluorescent dyes by replacement of the four oxygen atoms of the heterocyclic core by sulfur atoms. This variation causes striking changes of the photophysical properties. Whereas absorption and emission significantly shifted to longer wavelength, the fluorescence lifetimes and quantum yields are diminished compared to DBD dyes. The latter effect is presumably caused by an enhanced intersystem crossing to the triplet state due to the sulfur atoms. The very large Stokes shifts of the S4-DBD dyes ranging from 3000 cm–1 to 7400 cm–1 (67 nm to 191 nm) should be especially emphasized. By analogy with DBD dyes a broad variation of absorption and emission wavelength is possible by introducing different electron withdrawing substituents. Moreover, some derivatives for coupling with biomolecules were developed.