109010-32-4

Upstream product

• 86420-73-7 methyl 3-O-benzoyl-4,6-O-benzylidene-β-D-galactopyranoside 
• 64552-06-3 methyl 4,6-O-benzylidene-α-D-galactopyranoside 
• 98-88-4 benzoyl chloride 
• 613-90-1 benzoyl cyanide 
• 86420-71-5 methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-galactopyranoside 
• 71117-36-7 methyl 4,6-O-(S)-benzylidene-β-D-galactopyranoside 
• 91685-05-1 methyl 3-O-benzoyl-4, 6-O-benzylidene-α-D-mannopyranoside 
• 33535-04-5 methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside 

Downstream Products

• 86030-24-2 methyl 4,6-O-benzylidene-2,3-dideoxy-2-phenylazo-α-D-threo-hex-2-enopyranoside 
• 86030-32-2 methyl 3-benzylamino-4,6-O-benzylidene-3-deoxy-α-D-lyxo(or xylo)-hexopyranosidulose phenylhydrazone 
• 86030-30-0 methyl 4,6-O-benzylidene-3-deoxy-3-methylamino-α-D-lyxo(or xylo)-hexopyranosidulose phenylhydrazone 
• 86030-31-1 methyl 4,6-O-benzylidene-3-deoxy-3-dimethylamino-α-D-lyxo(or xylo)-hexopyranosidulose phenylhydrazone 
• 86030-33-3 methyl 4,6-O-benzylidene-3-deoxy-α-D-threo-hexopyranosidulose phenylhydrazone 
• 38993-10-1 methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-lyxo-hexopyranosidulose 4-nitrophenylhydrazone 
• 38993-06-5 methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-lyxo-hexopyranosidulose phenylhydrazone 
• 38993-10-1 methyl 3-O-benzoyl-4,6-O-benzylidene-β-D-lyxo-hexopyranosidulose 4-nitrophenylhydrazone 
• 86030-25-3 methyl 4,6-O-benzylidene-2,3-dideoxy-2-phenylazo-β-D-threo-hex-2-enopyranoside 
• 108947-21-3 Methyl-3-O-benzoyl-4,6-O-benzyliden-3-C-2-methyl-α-D-arabino-hexopyranosid-2-ulose 
• 61403-87-0 methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-lyxo-hexopyranosidulose 2,4-dinitrophenylhydrazone 
• 61403-87-0 methyl 3-O-benzoyl-4,6-O-benzylidene-β-D-lyxo-hexopyranosidulose 2,4-dinitrophenylhydrazone 

Relevant academic research and scientific papers

Intramolecular Hydrogen Atom Abstraction in Carbohydrates and Nucleosides: Inversion of an α- to β-Mannopyranoside and Generation of Thymidine C-4' Radicals

Treatment of 1-bromo-2-methyl-2-propyl ether derivatives of alcohols with Bu3SnH(D) results in 1,5-Hydrogen abstraction reactions: the system is applied to the inversion of an α- to β-mannoside and to the formation of nucleoside C4' radicals.

Enolates of carbohydrates, 5. Syntheses of axially methyl-branched pyranosiduloses

The α-C-methylated carbohydrates 3 and 5 are available from the benzoyl- and benzylidene protected 2- and 3-uloses 1a, 2, and 4 by reaction with potassium tert-butoxide/methyl iodide in N,N-dimethylformamide.Under pthe same conditions the 2-O-benzyl-3-ulose 1b yields the enol ether 6a, and the enolone 8 is obtained from the 2-O-benzoyl-3-ulose 7.

Arylazo-glycenosides. Part 8. Synthesis and Reactions of Some 2- and 3-Arylazo-derivatives of Methyl 4,6-O-Benzylidene-2,3-dideoxy-D-threo-hex-2-enopyranosides

Preparations are described of the α- and β-anomers of methyl 4,6-O-benzylidene-2,3-dideoxy-2-phenylazo-D-threo-hex-2-enopyranoside and of methyl 4,6-O-benzyliden-2,3-dideoxy-3-phenylazo-α-D-threo-hex-2-enopyranoside using D-galactose as the initial materi