109023-26-9Relevant academic research and scientific papers
Effect of a β-Silyl Group on the Regiochemistry of Enolisation of Ketones
Engel, Wolfhard,Fleming, Ian,Smithers, Roger H.
, p. 1637 - 1642 (2007/10/02)
1-Dimethyl(phenyl)silylpentan-3-one (4), 3-dimethyl(phenyl)silylcyclopentanone (10) and 3-dimethyl(phenyl)silylcyclohexanone (16) are deprotonated by lithium di-isopropylamide in favour of enolate formation away from the silyl group to the extent of 70:30
