109057-76-3Relevant academic research and scientific papers
Reactions of 1-nitrocyclohexene with N,N-binucleophiles
Efremova,Vakulenko,Lysenko,Bushmarinov,Lapshina,Berkova,Berestovitskaya
experimental part, p. 2298 - 2305 (2011/04/14)
A modification of 1-nitrocyclohexene synthesis is proposed; its reaction with phenylhydrazine and benzoic acid hydrazide is shown to afford monoadducts, and with hydrazine hydrate, bisaduct. With diphenylguanidine occurs heterocyclization to 1-phenyl-2-N-phenylamino-4,5,6,7-tetrahydrobenzimidazole, whose structure is confirmed by the X-ray diffraction data. The analysis performed for this compound of the electron density distribution function in the crystal made it possible to estimate the charge distribution, π-electrons delocalization nature, and the role of N-H···N, C-H···H-C and C-H···C interactions in the formation of the crystal packing. Pleiades Publishing, Ltd., 2010.
An Efficient Method for the Copper(II)-promoted Stereoselective Iodofunctionalization of Alkenes
Barluenga, Jose,Rodriguez, Miguel A.,Campos, Pedro J.
, p. 2807 - 2809 (2007/10/02)
A mixture of iodine and CuO*HBF4 reacts stereoselectively with alkenes in the presence of a wide variety of nucleophiles (water, MeOH, HCO2H, AcOH, EtCOOH, NaNO2, KSCN, NaSO2Ar, LiCl, LiBr, NaI, Et3SiH, and MeOPh) to give the corresponding 2-functionalized iodo compounds.A regio chemistry study is also reported.
A General and Useful Copper(II)-promoted Iodofunctionalization of Unsaturated Systems
Barluenga, Jose,Rodriguez, Miguel A.,Campos, Pedro J.,Asensio, Gregorio
, p. 1491 - 1492 (2007/10/02)
A mixture of iodine and CuO*HBF4 reacts stereospecifically with olefins in the presence of a wide variety of nucleophiles (NaNO2, NaSO2Ar, NaI, Et3SiH, MeOPh and H2O) to give the corresponding 2-functionalized iodo compounds; the same reagents also cause iodofunctionalization of 1,3-dienes and acetylenes.
A Practical Preparations of Conjugated Nitroalkenes
Jew, Sang-sup,Kim, Hee-doo,Cho, Youn-sang,Cook, Chae-ho
, p. 1747 - 1748 (2007/10/02)
Treatment of alkenes (1a-5a) with sodium nitrite and iodine in ethyl acetate (or ether) and water in the presence of ethylene glycol (or propylene glycol) provides conjugated nitroalkenes (1b-5b) in 49-82percent yields.
