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Mercury in organic chemistry. 34. Synthesis of vinylmercurials via mercuration of propargylic amines
Larock,Burns,Varaprath,Russell,Richardson Jr.,Janakiraman,Jacobson
, p. 1780 - 1789 (1987)
Propargylic amines react readily with 1-2 M HgCl2 in 2-6 M HCl to precipitate the ammonium trichloromercurate, bis(ammonium) tetrachloromercurate, or bis (ammonium) hexachlorodimercurate salts 1-10 in which mercuric chloride has added in a trans manner across the original carbon-carbon triple bond placing the mercury nearer to nitrogen. X-ray crystallographic data on one of each type of these salts are provided.
