Mercury in organic chemistry. 34. Synthesis of vinylmercurials via mercuration of propargylic amines

DOI: 10.1021/om00151a027

Source and publish data:

Organometallics p. 1780 - 1789 (1987)

Update date:2022-08-05

Topics:

Authors:

Larock Larock

Burns Burns

Varaprath

Russell Russell

Richardson Jr.

Janakiraman

Jacobson

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Article abstract of DOI:10.1021/om00151a027

Propargylic amines react readily with 1-2 M HgCl₂ in 2-6 M HCl to precipitate the ammonium trichloromercurate, bis(ammonium) tetrachloromercurate, or bis (ammonium) hexachlorodimercurate salts 1-10 in which mercuric chloride has added in a trans manner across the original carbon-carbon triple bond placing the mercury nearer to nitrogen. X-ray crystallographic data on one of each type of these salts are provided.

Full text of DOI:10.1021/om00151a027

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