Organometallics p. 1780 - 1789 (1987)
Update date:2022-08-05
Topics:
Larock
Burns
Varaprath
Russell
Richardson Jr.
Janakiraman
Jacobson
Propargylic amines react readily with 1-2 M HgCl2 in 2-6 M HCl to precipitate the ammonium trichloromercurate, bis(ammonium) tetrachloromercurate, or bis (ammonium) hexachlorodimercurate salts 1-10 in which mercuric chloride has added in a trans manner across the original carbon-carbon triple bond placing the mercury nearer to nitrogen. X-ray crystallographic data on one of each type of these salts are provided.
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Doi:10.1021/ja9108424
(2010)Doi:10.1021/acs.joc.5b02693
(2016)Doi:10.1055/s-2008-1078207
(2008)Doi:10.1021/ja805393b
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(2008)
