109105-52-4Relevant academic research and scientific papers
Synthesis of a 1,3,4,5-tetrahydrobenzindole β-ketoester
Rosenberg, Marianne Lenes,Aasheim, Jens H. F.,Trebbin, Martin,Uggerud, Einar,Hansen, Tore
supporting information; experimental part, p. 6506 - 6508 (2011/02/27)
Pd(OAc)2-catalyzed decomposition of ethyl 2-diazo-4-(4-indolyl)-3- oxobutanoate leads to a tricyclic tetrahydrobenzindole compound formed by a formal C-H insertion reaction. This tricyclic indole rearranges to a novel and thermodynamically more stable nap
SYNTHESIS OF 4-(4-INDOLYL)-3-OXOBUTANOIC ACID DERIVATIVES FROM 5-HALO-4-OXO-4,5,6,7-TETRAHYDROINDOLES
Matsumoto, Masakatsu,Watanabe, Nobuko
, p. 3149 - 3156 (2007/10/02)
The reaction of 5-halo-4-oxo-4,5,6,7,-tetrahydroindoles with dianion of acetoacetic acid esters or N,N-dimethylamide followed by dehydration and dehydrohalogenation gave 4-(4-indolyl)-3-oxobutanoic acid derivatives. 4-Acetonylindoles with benzoyl and p-to
