76989-06-5Relevant articles and documents
Synthesis of a 1,3,4,5-tetrahydrobenzindole β-ketoester
Rosenberg, Marianne Lenes,Aasheim, Jens H. F.,Trebbin, Martin,Uggerud, Einar,Hansen, Tore
experimental part, p. 6506 - 6508 (2011/02/27)
Pd(OAc)2-catalyzed decomposition of ethyl 2-diazo-4-(4-indolyl)-3- oxobutanoate leads to a tricyclic tetrahydrobenzindole compound formed by a formal C-H insertion reaction. This tricyclic indole rearranges to a novel and thermodynamically more stable nap
SELECTIVE CLEAVAGE OF UNSYMMETRICAL 2,2-SPIRO-1,3-DIOXOLANES. II. CLEAVAGE OF KETAL RING Of 5'-BROMO-6',7'-DIHYDRO-4-ISOPROPYLAMINOMETHYL-1'-p-TOLUENESULFONYL-SPIRO AND ITS ANALOGS
Sakai, Makiko
, p. 1269 - 1275 (2007/10/02)
The bromodioxolane and its analogs (1-5) were treated with organic base (DBU, DBN, or morpholine), acid (p-toluenesulfonic acid or Lewis acid), or Lewis acid/tertiary amine, and yielded 4-alkoxyindoles (6-17).Reaction of 1 with organic base gave two isome