76989-06-5

Basic information

• Product Name: 5-Bromo-1-tosyl-4,5,6,7-tetrahydro-1H-indol-4-one
• Synonyms: 5-Bromo-1-tosyl-4,5,6,7-tetrahydro-1H-indol-4-one
• CAS NO: 76989-06-5
• Molecular Formula: C₁₅H₁₄BrNO₃S
• Molecular Weight: 0
• Mol File: 76989-06-5.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 5-Bromo-1-tosyl-4,5,6,7-tetrahydro-1H-indol-4-one(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Bromo-1-tosyl-4,5,6,7-tetrahydro-1H-indol-4-one(76989-06-5)
• EPA Substance Registry System: 5-Bromo-1-tosyl-4,5,6,7-tetrahydro-1H-indol-4-one(76989-06-5)

Safety Data

• Hazardous Substances Data: 76989-06-5(Hazardous Substances Data)

Upstream product

• 76988-97-1 C₂₁H₂₇BrN₂O₄S 
• 76988-93-7 C₂₁H₂₈N₂O₄S 
• 35577-89-0 1-[(4-methylbenzene)sulfonyl]-4,5,6,7-tetrahydro-1H-indol-4-one 

Downstream Products

• 106486-86-6 5-bromo-4-(1,3-dithian-2-yl)-4-hydroxy-1-(p-toluenesulfonyl)-4,5,6,7-tetrahydroindole 
• 81038-34-8 1-(p-toluenesulphonyl)-4-hydroxyindole 
• 1198428-85-1 ethyl 2-diazo-4-(5'-brom-6',7'-dihydro-N-tosyl-indole-4'(5'H)-yliden)-3-oxobutanoate 
• 1198428-86-2 ethyl 2-diazo-4-(5'-brom-6',7'-dihydro-N-tosyl-indole-4'(5'H)-yliden)-3-oxobutanoate 
• 1198428-84-0 ethyl 2-diazo-4-(5'-bromo-4',5',6',7'-tetrahydro-4'-hydroxy-N-tosyl-indole-4'-yl)-3-oxobutanoate 
• 106486-88-8 4-(1,3-dithian-2-yl)-1-(p-toluenesulfonyl)indole 
• 79681-04-2 1-[(4-methyl-phenyl)-sulfonyl]-1H-indol-4-carboxaldehyde 
• 1074-86-8 4-formyl indole 

Relevant articles and documents

Synthesis of a 1,3,4,5-tetrahydrobenzindole β-ketoester

Pd(OAc)2-catalyzed decomposition of ethyl 2-diazo-4-(4-indolyl)-3- oxobutanoate leads to a tricyclic tetrahydrobenzindole compound formed by a formal C-H insertion reaction. This tricyclic indole rearranges to a novel and thermodynamically more stable nap

Selective halogenation of 4-oxo-4,5,6,7-tetrahydroindoles to 5-halo-4-oxo-4,5,6,7-tetrahydroindoles with copper(II) halides

Halogenation of 4-oxo-4,5,6,7-tetrahydroindoles with copper(II) bromide or copper(II) chloride gave selectively 5-halo-4-oxo-4,5,6,7-tetrahydroindoles, which were easily transformed to 4-hydroxyindoles by the action of lithium halide/lithium carbonate in

SELECTIVE CLEAVAGE OF UNSYMMETRICAL 2,2-SPIRO-1,3-DIOXOLANES. II. CLEAVAGE OF KETAL RING Of 5'-BROMO-6',7'-DIHYDRO-4-ISOPROPYLAMINOMETHYL-1'-p-TOLUENESULFONYL-SPIRO AND ITS ANALOGS

The bromodioxolane and its analogs (1-5) were treated with organic base (DBU, DBN, or morpholine), acid (p-toluenesulfonic acid or Lewis acid), or Lewis acid/tertiary amine, and yielded 4-alkoxyindoles (6-17).Reaction of 1 with organic base gave two isome