Cas 109124-80-3,(RuH(NH2CH2CH3)2(CH3C(CH2As(C6H5)2)3))(1+)*CF3SO3(1-)=(RuH(NH2CH2CH3)2(CH3C(CH2As(C6H5)2)3))CF3SO3

109124-80-3

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Product Name: (RuH(NH₂CH₂CH₃)2(CH₃C(CH₂As(C₆H₅)2)3))⁽¹⁺⁾*CF₃SO₃^(1-)=(RuH(NH₂CH₂CH₃)2(CH₃C(CH₂As(C₆H₅)2)3))CF₃SO₃
Synonyms: (RuH(NH₂CH₂CH₃)2(CH₃C(CH₂As(C₆H₅)2)3))⁽¹⁺⁾*CF₃SO₃^(1-)=(RuH(NH₂CH₂CH₃)2(CH₃C(CH₂As(C₆H₅)2)3))CF₃SO₃
CAS NO:109124-80-3
Molecular Formula:
Molecular Weight: 1097.84
EINECS: N/A
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Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (RuH(NH₂CH₂CH₃)2(CH₃C(CH₂As(C₆H₅)2)3))⁽¹⁺⁾*CF₃SO₃^(1-)=(RuH(NH₂CH₂CH₃)2(CH₃C(CH₂As(C₆H₅)2)3))CF₃SO₃(CAS DataBase Reference)
NIST Chemistry Reference: (RuH(NH₂CH₂CH₃)2(CH₃C(CH₂As(C₆H₅)2)3))⁽¹⁺⁾*CF₃SO₃^(1-)=(RuH(NH₂CH₂CH₃)2(CH₃C(CH₂As(C₆H₅)2)3))CF₃SO₃(109124-80-3)
EPA Substance Registry System: (RuH(NH₂CH₂CH₃)2(CH₃C(CH₂As(C₆H₅)2)3))⁽¹⁺⁾*CF₃SO₃^(1-)=(RuH(NH₂CH₂CH₃)2(CH₃C(CH₂As(C₆H₅)2)3))CF₃SO₃(109124-80-3)

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Safety Statements: N/A
WGK Germany:
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HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 109124-80-3(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 109124-80-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,9,1,2 and 4 respectively; the second part has 2 digits, 8 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 109124-80:
(8*1)+(7*0)+(6*9)+(5*1)+(4*2)+(3*4)+(2*8)+(1*0)=103
103 % 10 = 3
So 109124-80-3 is a valid CAS Registry Number.

109124-80-3Upstream product

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109124-80-3Relevant academic research and scientific papers

Ruthenium(II)-assisted borohydride reduction of acetonitrile

Rhodes, Larry F.,Venanzi, Luigi M.

, p. 2692 - 2695 (2008/10/08)

The sodium borohydride reduction of [Ru(MeCN)3(triars)](CF3SO3)2 (triars = MeC(CH2AsPh2)3) in methanol yields the bis(amine) hydride [RuH(NH2CH2Me)2(triars)](CF3SO 3). The amine and methylene protons are inequivalent on the NMR time scale up to +80°C. Deuterium substitution studies support the intermediacy of a metal-imine complex in the reduction. By contrast, reaction of NaBH4 and [Ru(MeCN)3(triphos)](CF3SO3)2 (triphos = MeC(CH2PPh2)3) gives the hydride borohydride complex [RuH(BH4)(triphos)]. NMR and GC measurements prove that MeCN is not reduced to amine in this case. The difference in reactivity is attributed to the difference in trans effects of the phosphorus and arsenic donors.

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