109144-16-3

Basic information

• Product Name: AlCl₃F^(1-)
• Synonyms: AlCl₃F^(1-)
• CAS NO: 109144-16-3
• Molecular Weight: 152.339
• Mol File: 109144-16-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: AlCl₃F^(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: AlCl₃F^(1-)(109144-16-3)
• EPA Substance Registry System: AlCl₃F^(1-)(109144-16-3)

Safety Data

• Hazardous Substances Data: 109144-16-3(Hazardous Substances Data)

Upstream product

• 7446-70-0 aluminium trichloride 
• 7784-16-9 sodium tetrachloroaluminate 

Relevant articles and documents

Aluminium-27 N.M.R. Studies of Aluminium Fluoro Complexes in Dichloromethane Solution: Evidence for the Tetrafluoroaluminate Anion

Mixed aluminium chloro/fluoro anions are formed in dichloromethane solution by the interaction of AlCl3 and .Aluminium-27 n.m.r. studies are restricted to the stoichiometric ranges F/Al from 1:1 to 3:1 and F/Al>8:1.Between these limits rapid precipitation reactions occur.In the Fluoride-rich stoichiometric range there is rapid exchange on the n.m.r. time scale between the aluminium fluoro anion and free fluoride, so that a direct identification of the species by the multiplicity of the resonance is not possible.Indirect evidence strongly suggests that the aluminium species is -.In the F/Al stoichiometry range from 1:1 to 3:1 aluminium-27 resonances were observed for all the other possible - species.Studies on the aluminium iodo/fluoro system support the identification of -, but the system is labile and the mixed iodo/fluoro species undergo rapid disproportionation.