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Aluminium chloride 7446-70-0 /manufacturer/low price/high quality/in stock
Cas No: 7446-70-0
USD $ 11.0-12.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Hangzhou Dayangchem Co., Ltd. Contact Supplier
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No Data 25 Kilogram 1000 Metric Ton/Week Shaanxi Mingqi Chemical Co., Ltd Contact Supplier
Aluminium chloride
Cas No: 7446-70-0
No Data 1 Kilogram 1 Metric Ton/Month HANGZHOU YUNUO CHEMICAL CO.,LTD Contact Supplier
POLY ALUMINUM CHLORIDE (PAC)
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No Data No Data Metric Ton/Day Weifang kaihong Chemical Co., Ltd. Contact Supplier
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USD $ 1.0-3.0 / Kilogram 1 Kilogram 10 Kilogram/Day Hebei yanxi chemical co.,LTD. Contact Supplier
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No Data 1 Kilogram 30 Metric Ton/Month Simagchem Corporation Contact Supplier
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No Data 1 Metric Ton 1000 Metric Ton/Year Hefei TNJ chemical industry co.,ltd Contact Supplier
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USD $ 2.5-3.0 / Kilogram 100 Kilogram 1000 Metric Ton/Year Wuhan Fortuna Chemical Co.,Ltd Contact Supplier
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Aluminium chloride
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No Data 1 Kilogram 300 Metric Ton/Year Jinan Finer Chemical Co., Ltd Contact Supplier

7446-70-0 Usage

Reaction

Reacts with calcium and magnesium hydrides in tetrahydrofuran forming tetrahydro aluminates, Ca(AlH4)2; reacts with hydrides of alkali metals in ether forming aluminum hydride;
Hydrolyzes in chilled, dilute HCl forming aluminum chloride hexahydrate, AlCl3⋅6H2O; reacts violently with water, evolving HCl,
AlCl3 + H2O ——› Al(OH)3 + HCl ↑

Description

White or light-yellow crystalline solid (or amorphous solid depending on the method of production); odor of HCl; hygroscopic; melts at 190°C at 2.5 atm; sublimes at 181.2°C; density 2.44 g/cm3 at 25°C; decomposes in water evolving heat; soluble in HCl; soluble in many organic solvents, including absolute ethanol, chloroform, carbon tetrachloride and ether; slightly soluble in benzene.
Aluminum chloride reacts vigorously with water and fumes in air. It is used as a catalyst in cracking petroleum and in organic synthesis.

Uses

Aluminum chloride has extensive commercial applications. It is used primarily in the electrolytic production of aluminum. Another major use involves its catalytic applications in many organic reactions, including Friedel-Crafts alkylation, polymerization, isomerization, hydrocracking, oxidation, decarboxylation, and dehydrogenation. It is also used in the production of rare earth chlorides, electroplating of aluminum and in many metal finishing and metallurgical operations.

Health Hazard

Contact with the skin or eyes in the presence of moisture causes thermal and acid burns.

Fire Hazard

Behavior in Fire: Reacts violently with water used in extinguishing adjacent fires

Preparation

Aluminum chloride is made by chlorination of molten aluminum at temperatures between 650 to 750°C;
2 Al + 3Cl2→ 2AlCl3
or by chlorination of alumina (bauxite or clay) at 800°C in the presence of a reducing agent, such as carbon or CO. It can be prepared by similar high temperature chlorination of bauxite in the presence of a chlorinated organic reductant such as CCl4.
A pelletized mixture of clay, lignite and a small amount of NaCl is chlorinated at 900°C, producing gaseous AlCl3 (Toth process). Alternatively, alumina is mixed with about 20% by weight carbon and a small amount of sodium salt. The mixture is chlorinated at 600°C (Bayer process).
In the laboratory, anhydrous AlCl3 can be prepared by heating the metal with dry HCl gas at 150°C. The product sublimes and deposits in the cool air condenser. Unreacted HCl is vented out.

Uses

Astringent (topical).

Purification Methods

Sublime it several times in an all-glass system under nitrogen at 30-50mm pressure. It has also been sublimed in a stream of dry HCl and has been subjected to a preliminary sublimation through a section of granular aluminium metal [for manipulative details see Jensen J Am Chem Soc 79 1226 1957]. It fumes in moist air.

Reactivity Profile

ALUMINUM CHLORIDE behaves as an acidic salt. Self-reactive. After long storage in closed containers, explosions often occur upon opening [Chem. Abst. 41:6723d 1947]. Can cause ethylene(also other alkenes) to polymerize violently [J. Inst. Pet. 33:254 1947]. Causes ethylene oxide to rearrange and polymerize, liberating heat [J. Soc. Chem. Ind. 68:179 1949]. Can catalyze violent polymerization of allyl chloride [Ventrone 1971]. Addition to nitrobenzene containing about 5% phenol caused a violent explosion [Chem. Eng. News 31:4915 1953]. Mixtures with nitromethane may explode when organic matter is present [Chem. Eng. News 26:2257 1948].
InChI:InChI=1/Al.3ClH.3H/h;3*1H;;;/p-3/rAlH3.3ClH/h1H3;3*1H/p-3

7446-70-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Fluka (06220)  Aluminumchloride  puriss. p.a., anhydrous, crystallized, ≥99.0% (AT) 7446-70-0 06220-2.5KG 2,226.51CNY Detail
Fluka (06220)  Aluminumchloride  puriss. p.a., anhydrous, crystallized, ≥99.0% (AT) 7446-70-0 06220-1KG 1,187.55CNY Detail
Fluka (06220)  Aluminumchloride  puriss. p.a., anhydrous, crystallized, ≥99.0% (AT) 7446-70-0 06220-100G 687.96CNY Detail
Sigma-Aldrich (06154)  AluminumstandardforAAS  analytical standard, traceable to BAM 7446-70-0 06154-500ML 589.68CNY Detail
Sigma-Aldrich (06154)  AluminumstandardforAAS  analytical standard, traceable to BAM 7446-70-0 06154-100ML 216.45CNY Detail
Sigma-Aldrich (11019)  Aluminumchloride  anhydrous, sublimed, ≥98% 7446-70-0 11019-6X1KG 4,470.57CNY Detail
Sigma-Aldrich (11019)  Aluminumchloride  anhydrous, sublimed, ≥98% 7446-70-0 11019-1KG 1,116.18CNY Detail
Sigma-Aldrich (11019)  Aluminumchloride  anhydrous, sublimed, ≥98% 7446-70-0 11019-500G 744.12CNY Detail
Sigma-Aldrich (206911)  Aluminumchloride  reagent grade, 98% 7446-70-0 206911-1KG 965.25CNY Detail
Sigma-Aldrich (206911)  Aluminumchloride  reagent grade, 98% 7446-70-0 206911-100G 497.25CNY Detail
Sigma-Aldrich (237051)  Aluminumchloride  ReagentPlus®, 99% 7446-70-0 237051-500G 1,172.34CNY Detail
Sigma-Aldrich (237051)  Aluminumchloride  ReagentPlus®, 99% 7446-70-0 237051-100G 618.93CNY Detail

7446-70-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name aluminium trichloride

1.2 Other means of identification

Product number -
Other names Aluminium chloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7446-70-0 SDS

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