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Aluminium chloride
Cas No: 7446-70-0
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Aluminium chloride
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High quality Aluminium Chloride supplier in China
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Aluminium chloride CAS NO.7446-70-0
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Aluminum chloride CAS:7446-70-0
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Aluminium chloride
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AluMinuM chloride
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7446-70-0 Usage

Health Hazard

Contact with the skin or eyes in the presence of moisture causes thermal and acid burns.

Fire Hazard

Behavior in Fire: Reacts violently with water used in extinguishing adjacent fires

Incompatibilities

A strong reducing agent. Contact with air or water forms hydrochloric acid and hydrogen chloride gas. Reaction with water may be violent. Water, alcohol, and alkenes can cause polymerization. Incompatible with nitrobenzene, organic material, and bases. Attacks metal in presence of moisture, forming flammable hydrogen gas.

Uses

Astringent (topical).

Reaction

Reacts with calcium and magnesium hydrides in tetrahydrofuran forming tetrahydro aluminates, Ca(AlH4)2; reacts with hydrides of alkali metals in ether forming aluminum hydride; Hydrolyzes in chilled, dilute HCl forming aluminum chloride hexahydrate, AlCl3?6H2O; reacts violently with water, evolving HCl, AlCl3 + H2O ——? Al(OH)3 + HCl ↑

Industrial uses

Aluminium trichloride (AlCl3) act as Lewis acids to a wide range of electron-pair donors, and this has led to their widespread use as catalysts. In the important Friedel–Crafts acylation, AlCl3 is used as a strong Lewis acid catalyst in order to achieve the acylation of an aromatic ring.

Shipping

UN1726 Aluminum chloride, anhydrous, Hazard class: 8; Labels: 8-Corrosive material. UN2581 Aluminum chloride solution, Hazard class: 8; Labels: 8-Corrosive material

Industrial uses

Aluminum chloride (AlCl3) is a volatile solid which sublimes at 458 K. The vapour formed on sublimation consists of an equilibrium mixture of monomers (AlCl3) and dimers (Al2Cl6). It is used to prepare the powerful and versatile reducing agent lithium tetrahydridoaluminate (LiAlH4). Aluminium trichloride (AlCl3) act as Lewis acids to a wide range of electron-pair donors, and this has led to their widespread use as catalysts. In the important Friedel-Crafts acylation, AlCl3 is used as a strong Lewis acid catalyst in order to achieve the acylation of an aromatic ring.

Preparation

Aluminum chloride is made by chlorination of molten aluminum at temperatures between 650 to 750°C; 2 Al + 3Cl2→ 2AlCl3 or by chlorination of alumina (bauxite or clay) at 800°C in the presence of a reducing agent, such as carbon or CO. It can be prepared by similar high temperature chlorination of bauxite in the presence of a chlorinated organic reductant such as CCl4. A pelletized mixture of clay, lignite and a small amount of NaCl is chlorinated at 900°C, producing gaseous AlCl3 (Toth process). Alternatively, alumina is mixed with about 20% by weight carbon and a small amount of sodium salt. The mixture is chlorinated at 600°C (Bayer process). In the laboratory, anhydrous AlCl3 can be prepared by heating the metal with dry HCl gas at 150°C. The product sublimes and deposits in the cool air condenser. Unreacted HCl is vented out.

Flammability and Explosibility

Aluminum chloride is not flammable but reacts violently with water, so fires involving this substance should be extinguished with carbon dioxide or dry chemicals. Toxic fumes (HCl and reaction products) can be released during fires.

storage

work with this substance should be conducted in a fume hood, and impermeable gloves should be worn at all times when handling AlCl3. Aluminum chloride should be stored in sealed containers under an inert atmosphere in a cool, dry place. Care should be taken in opening containers of this compound because of the possibility of the buildup of HCl vapor from hydrolysis with traces of moisture.

Uses

Aluminum chloride has extensive commercial applications. It is used primarily in the electrolytic production of aluminum. Another major use involves its catalytic applications in many organic reactions, including Friedel-Crafts alkylation, polymerization, isomerization, hydrocracking, oxidation, decarboxylation, and dehydrogenation. It is also used in the production of rare earth chlorides, electroplating of aluminum and in many metal finishing and metallurgical operations.

Safety Profile

Moderately toxic by ingestion. Experimental teratogenic and reproductive effects. Mutation data reported. The dust is an irritant by ingestion, inhalation, and skin contact. Highly exothermic polymerization reactions with alkenes. Incompatible with nitrobenaenes or nitrobenzene + phenol. Highly exothermic reaction with water or steam produces toxic fumes of HCl. See also ALUMINUM COMPOUNDS, CHLORIDES, and HYDROCHLORIC ACID.

Reactivity Profile

ALUMINUM CHLORIDE behaves as an acidic salt. Self-reactive. After long storage in closed containers, explosions often occur upon opening [Chem. Abst. 41:6723d 1947]. Can cause ethylene(also other alkenes) to polymerize violently [J. Inst. Pet. 33:254 1947]. Causes ethylene oxide to rearrange and polymerize, liberating heat [J. Soc. Chem. Ind. 68:179 1949]. Can catalyze violent polymerization of allyl chloride [Ventrone 1971]. Addition to nitrobenzene containing about 5% phenol caused a violent explosion [Chem. Eng. News 31:4915 1953]. Mixtures with nitromethane may explode when organic matter is present [Chem. Eng. News 26:2257 1948].

Hazard

Powerful irritant to tissue; moderately toxic by ingestion. Reacts violently with water, evolving hydrogen chloride gas.

Uses

Aluminum chloride is used as a catalyst in many organic reactions.

Uses

A yellowish-white crystalline or granular powder made by passing chlorine gas over alumina in a heated state and collecting the product by sublimation. Aluminum chloride was occasionally used in gold and platinum toning baths.

Purification Methods

Sublime it several times in an all-glass system under nitrogen at 30-50mm pressure. It has also been sublimed in a stream of dry HCl and has been subjected to a preliminary sublimation through a section of granular aluminium metal [for manipulative details see Jensen J Am Chem Soc 79 1226 1957]. It fumes in moist air.

Potential Exposure

It is used as ethylbenzene catalyst, dyestuff intermediate, and detergent alkylate; in making other chemicals and dyes, astringents, deodorants, in the petroleum refining, and the rubber industries

Description

White or light-yellow crystalline solid (or amorphous solid depending on the method of production); odor of HCl; hygroscopic; melts at 190°C at 2.5 atm; sublimes at 181.2°C; density 2.44 g/cm3 at 25°C; decomposes in water evolving heat; soluble in HCl; soluble in many organic solvents, including absolute ethanol, chloroform, carbon tetrachloride and ether; slightly soluble in benzene. Aluminum chloride is important industrial chemical. Anhydrous Aluminum chloride is used as the catalyst in variety of Friedel-Crafts type of reactions. Large amounts of ethylbenzene are prepared in this way and are used to make styrene. C6H6 + CH3CH2Cl + AlCl3→C6H5CH2CH3 + H+ + [AlCl4]- Aluminum chloride is also used in the manufacture of anthraquinone (used in dyestuffs industry) and dodecylbenzene (used to make detergents) and in the isomerisation of hydrocarbons (petroleum industry). Aluminum chloride reacts vigorously with water and fumes in air. It is used as a catalyst in cracking petroleum and in organic synthesis.

Definition

aluminium chloride: A whitishsolid, AlCl3, which fumes in moist airand reacts violently with water (togive hydrogen chloride). It is knownas the anhydrous salt (hexagonal; r.d.2.44 (fused solid); m.p. 190°C (2.5atm.); sublimes at 178°C) or the hexahydrateAlCl3.6H2O (rhombic; r.d.2.398; loses water at 100°C), both ofwhich are deliquescent. Aluminiumchloride may be prepared by passinghydrogen chloride or chlorine overhot aluminium or (industrially) bypassing chlorine over heated aluminiumoxide and carbon. The chlorideion is polarized by the smallpositive aluminium ion and thebonding in the solid is intermediatebetween covalent and ionic. In theliquid and vapour phases dimer moleculesexist, Al2Cl6, in which thereare chlorine bridges making coordinatebonds to aluminium atoms (seeformula). The AlCl3 molecule can alsoform compounds with other moleculesthat donate pairs of electrons(e.g. amines or hydrogen sulphide);i.e. it acts as a Lewis acid. At hightemperatures the Al2Cl6 molecules inthe vapour dissociate to (planar)AlCl3 molecules. Aluminium chlorideis used commercially as a catalyst inthe cracking of oils. It is also a catalystin certain other organic reactions,especially the Friedel–Craftsreaction.

Waste Disposal

May be sprayed with aqueous ammonia in the presence of ice and, when reaction is complete, flushed down drain with running water.

Chemical Properties

Aluminum chloride is a noncombustible but highly reactive whitish-gray, yellow, or green powder or liquid. Strong, acidic, irritating odor like hydrochloric acid.The vapor consists of double molecules Al2Cl6 . Soluble in water.
InChI:InChI=1/Al.3ClH.3H/h;3*1H;;;/p-3/rAlH3.3ClH/h1H3;3*1H/p-3

7446-70-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (44313)  Aluminum chloride, ultra dry, 99.999% (metals basis)    7446-70-0 25g 1807.0CNY Detail
Alfa Aesar (44313)  Aluminum chloride, ultra dry, 99.999% (metals basis)    7446-70-0 100g 5469.0CNY Detail
Alfa Aesar (14552)  Aluminum chloride, ultra dry, 99.99% (metals basis)    7446-70-0 5g 630.0CNY Detail
Alfa Aesar (14552)  Aluminum chloride, ultra dry, 99.99% (metals basis)    7446-70-0 25g 1652.0CNY Detail
Alfa Aesar (14552)  Aluminum chloride, ultra dry, 99.99% (metals basis)    7446-70-0 100g 4815.0CNY Detail
Alfa Aesar (88488)  Aluminum chloride, anhydrous, 99.985% (metals basis)    7446-70-0 5g 296.0CNY Detail
Alfa Aesar (88488)  Aluminum chloride, anhydrous, 99.985% (metals basis)    7446-70-0 50g 564.0CNY Detail
Alfa Aesar (88488)  Aluminum chloride, anhydrous, 99.985% (metals basis)    7446-70-0 250g 1511.0CNY Detail
Alfa Aesar (44470)  Aluminum chloride, anhydrous, 99.999% (metals basis)    7446-70-0 5g 402.0CNY Detail
Alfa Aesar (44470)  Aluminum chloride, anhydrous, 99.999% (metals basis)    7446-70-0 25g 952.0CNY Detail
Alfa Aesar (44470)  Aluminum chloride, anhydrous, 99.999% (metals basis)    7446-70-0 100g 2876.0CNY Detail
Alfa Aesar (89914)  Aluminum chloride, anhydrous, 95+%    7446-70-0 1kg 296.0CNY Detail

7446-70-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name aluminium trichloride

1.2 Other means of identification

Product number -
Other names Aluminium chloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7446-70-0 SDS

7446-70-0Synthetic route

chlorine
7782-50-5

chlorine

aluminium
7429-90-5

aluminium

aluminium trichloride
7446-70-0

aluminium trichloride

Conditions
ConditionsYield
In neat (no solvent) passing a flow of Cl2 over Al in a combustion tube;;80%
In neat (no solvent) heating Al shavings in a flow of chlorine; distd. in vac.;
at 600 K;
phosgene
75-44-5

phosgene

aluminium bromide
7727-15-3

aluminium bromide

A

aluminium trichloride
7446-70-0

aluminium trichloride

B

carbonyl bromide chloride
7726-12-7

carbonyl bromide chloride

Conditions
ConditionsYield
equil. amts of educts in tube, cooling than 140-145°C, 7-8h; distn., addn. Hg, distn. 24.5-25.5°C atmospheric pressure;A n/a
B 50%
equil. amts of educts in tube, cooling than 140-145°C, 7-8h; distn., addn. Hg, distn. 24.5-25.5°C atmospheric pressure;A n/a
B 50%
lithium aluminium tetrahydride
16853-85-3

lithium aluminium tetrahydride

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

A

aluminium trichloride
7446-70-0

aluminium trichloride

B

phosphan
7803-51-2

phosphan

C

lithium chloride

lithium chloride

Conditions
ConditionsYield
In diethyl ether reduction of PCl3 with LiAlH4 in ether at 0 °C;;
In diethyl ether reduction of PCl3 with LiAlH4 in ether at 75 °C;;A n/a
B 0.25%
C n/a
In diethyl ether reduction of PCl3 with LiAlH4 in ether at 75 °C;;A n/a
B 0.25%
C n/a
In diethyl ether reduction of PCl3 with LiAlH4 in ether at 0 °C;;
8-chloro-1-methoxy-phenazine
14202-90-5

8-chloro-1-methoxy-phenazine

A

aluminium trichloride
7446-70-0

aluminium trichloride

B

8-chloro-phenazin-1-ol
23663-42-5

8-chloro-phenazin-1-ol

Conditions
ConditionsYield
With benzene
1,3,5-trichloro-2,4,6-triazine
108-77-0

1,3,5-trichloro-2,4,6-triazine

diethyl ether
60-29-7

diethyl ether

LiAlH4

LiAlH4

A

aluminium trichloride
7446-70-0

aluminium trichloride

B

LiCl

LiCl

C

lithium tetracyanoalanate

lithium tetracyanoalanate

methylbutane
78-78-4

methylbutane

tertiary butyl chloride
507-20-0

tertiary butyl chloride

aluminium bromide
7727-15-3

aluminium bromide

A

aluminium trichloride
7446-70-0

aluminium trichloride

B

Isobutane
75-28-5

Isobutane

C

2-bromo-2-methylbutane
507-36-8

2-bromo-2-methylbutane

D

3-bromo-2-methylbutane
18295-25-5, 26561-37-5

3-bromo-2-methylbutane

hydrogenchloride
7647-01-0

hydrogenchloride

ethyl 2-ethoxy-2-iminoacetate
816-27-3

ethyl 2-ethoxy-2-iminoacetate

A

aluminium trichloride
7446-70-0

aluminium trichloride

B

oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

2,2-diphenylpropane
778-22-3

2,2-diphenylpropane

2-methyl-2-phenylpropanoyl chloride
36293-05-7

2-methyl-2-phenylpropanoyl chloride

carbon monoxide

carbon monoxide

A

aluminium trichloride
7446-70-0

aluminium trichloride

B

benzene
71-43-2

benzene

2,4,6-Trimethylacetophenone
1667-01-2

2,4,6-Trimethylacetophenone

propionyl chloride
79-03-8

propionyl chloride

A

aluminium trichloride
7446-70-0

aluminium trichloride

B

1,3-dipropionyl-2,4,6-trimethylbenzene
6335-36-0

1,3-dipropionyl-2,4,6-trimethylbenzene

propionyl chloride
79-03-8

propionyl chloride

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

A

aluminium trichloride
7446-70-0

aluminium trichloride

B

1,3-dipropionyl-2,4,6-trimethylbenzene
6335-36-0

1,3-dipropionyl-2,4,6-trimethylbenzene

water
7732-18-5

water

acenaphthen-5-yl-phenyl ketone; compound with aluminium trichloride

acenaphthen-5-yl-phenyl ketone; compound with aluminium trichloride

A

aluminium trichloride
7446-70-0

aluminium trichloride

B

5-benzoylacenaphthene
4657-89-0

5-benzoylacenaphthene

6-Acetyl-1,2,3,4-tetrahydronaphthalene
774-55-0

6-Acetyl-1,2,3,4-tetrahydronaphthalene

diethyl ether
60-29-7

diethyl ether

acetyl chloride
75-36-5

acetyl chloride

A

aluminium trichloride
7446-70-0

aluminium trichloride

B

2,5-diacetyl-7-ethyl-1-methyl-indene
101431-21-4

2,5-diacetyl-7-ethyl-1-methyl-indene

5-benzoyl-2,4-dibromo-benzoyl chloride

5-benzoyl-2,4-dibromo-benzoyl chloride

A

aluminium trichloride
7446-70-0

aluminium trichloride

B

1-benzoyl-2,4-dibromo-5-(2,4-dimethyl-benzoyl)-benzene
110877-20-8

1-benzoyl-2,4-dibromo-5-(2,4-dimethyl-benzoyl)-benzene

Conditions
ConditionsYield
With m-xylene
phosgene
75-44-5

phosgene

monoaluminum phosphate

monoaluminum phosphate

chlorine
7782-50-5

chlorine

A

aluminium trichloride
7446-70-0

aluminium trichloride

Conditions
ConditionsYield
In neat (no solvent) reaction at at temperatures higher than 300°C;;
monoaluminum phosphate

monoaluminum phosphate

carbon monoxide
201230-82-2

carbon monoxide

chlorine
7782-50-5

chlorine

A

aluminium trichloride
7446-70-0

aluminium trichloride

Conditions
ConditionsYield
In neat (no solvent) reaction at at temperatures higher than 300°C;;
monoaluminum phosphate

monoaluminum phosphate

chlorine
7782-50-5

chlorine

A

aluminium trichloride
7446-70-0

aluminium trichloride

Conditions
ConditionsYield
With pyrographite In neat (no solvent) reaction at temperatures higher than 300°C;;
aluminum sulfide

aluminum sulfide

ammonium chloride

ammonium chloride

aluminium trichloride
7446-70-0

aluminium trichloride

aluminum oxide
1333-84-2, 1344-28-1

aluminum oxide

ammonium chloride

ammonium chloride

aluminium trichloride
7446-70-0

aluminium trichloride

Conditions
ConditionsYield
In neat (no solvent) calcination of NH4Cl and Al2O3;;
ammonium chloride

ammonium chloride

aluminium
7429-90-5

aluminium

aluminium trichloride
7446-70-0

aluminium trichloride

Conditions
ConditionsYield
In neat (no solvent) mixture contg. 45-50 weight-% Al-powder, 45 weight-% Al2O3 and 5-10 weight-% NH4Cl is heated to 600-830 °C yielding AlCl3 vapors;; not isolated;;
aluminum(III) sulfate

aluminum(III) sulfate

ammonium chloride

ammonium chloride

aluminium trichloride
7446-70-0

aluminium trichloride

Conditions
ConditionsYield
260°C; distillation of AlCl3;
In neat (no solvent) calcination of NH4Cl and Al2(SO4)3;;
aluminum sulfide

aluminum sulfide

aluminium trichloride
7446-70-0

aluminium trichloride

Conditions
ConditionsYield
With sodium chloride heating;
With hydrogenchloride HCl vapor;
With potassium chloride byproducts: K2S;
aluminum sulfide

aluminum sulfide

potassium chloride

potassium chloride

aluminium trichloride
7446-70-0

aluminium trichloride

aluminum sulfide

aluminum sulfide

sodium chloride
7647-14-5

sodium chloride

aluminium trichloride
7446-70-0

aluminium trichloride

aluminum sulfide

aluminum sulfide

barium(II) chloride

barium(II) chloride

aluminium trichloride
7446-70-0

aluminium trichloride

aluminum sulfide

aluminum sulfide

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

aluminium trichloride
7446-70-0

aluminium trichloride

aluminum sulfide

aluminum sulfide

iron(III) chloride
7705-08-0

iron(III) chloride

aluminium trichloride
7446-70-0

aluminium trichloride

hydrogenchloride
7647-01-0

hydrogenchloride

aluminum sulfide

aluminum sulfide

aluminium trichloride
7446-70-0

aluminium trichloride

Conditions
ConditionsYield
500°C;
500°C;
aluminum sulfide

aluminum sulfide

chlorine
7782-50-5

chlorine

aluminium trichloride
7446-70-0

aluminium trichloride

Conditions
ConditionsYield
95°C;
95°C;
aluminium trichloride
7446-70-0

aluminium trichloride

aluminium
7429-90-5

aluminium

Conditions
ConditionsYield
With hydrogen In neat (no solvent) byproducts: HCl; other Radiation; AlCl3 powder placed in quartz tube; tube evacuated and flushed with Ar and then heated under Ar/H2 flow to 90°C; rf discharge ignited for20 min and tube then cooled; XRD;100%
With potassium In neat (no solvent) heating AlCl3 in a rectangular glass tube and passing the vapor over pieces of K in the horizontal part of the tube;;
With lithium hydride; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride In neat (no solvent) mixed by stirring; deposited at 25-45°C for 15 min - 2 h;
aluminium trichloride
7446-70-0

aluminium trichloride

thiophenol
108-98-5

thiophenol

aluminium trichloride*thiophenol
36453-29-9

aluminium trichloride*thiophenol

Conditions
ConditionsYield
In benzene under N2, dropwise addn. of thiol soln. to a suspension of AlCl3 in benzene, dissoln.of AlCl3, stirred for 15 min at room temp.; evapn. of solvent, dried in vac. at room temp. for 3h, elem. anal.;100%
aluminium trichloride
7446-70-0

aluminium trichloride

praseodymium(III) chloride
10361-79-2

praseodymium(III) chloride

acetonitrile
75-05-8

acetonitrile

Pr(NCCH3)9(3+)*3AlCl4(1-)*CH3CN = [Pr(NCCH3)9](AlCl4)3*CH3CN

Pr(NCCH3)9(3+)*3AlCl4(1-)*CH3CN = [Pr(NCCH3)9](AlCl4)3*CH3CN

Conditions
ConditionsYield
In acetonitrile (inert atmosphere); condensing MeCN onto AlCl3 and PrCl3, reflux until aclear soln. is obtained; solvent removal (vac.); elem. anal.;100%
aluminium trichloride
7446-70-0

aluminium trichloride

ethanethiol
75-08-1

ethanethiol

aluminiumtrichloride*ethanediol
115958-68-4, 98772-97-5

aluminiumtrichloride*ethanediol

Conditions
ConditionsYield
In benzene slow addn. of ethanethiol to a suspn. of an equimolar amt. of AlCl3 in benzene; mixt. stirred for 1 h at room temp.; solvent distd. off in vac. at 60°C; residual oil distd. at 86°C (0.5 Torr); elem. anal.;100%
In benzene under N2, dropwise addn. of thiol soln. to a suspension of AlCl3 in benzene, dissoln.of AlCl3, stirred for 15 min at room temp.; evapn. of solvent, dried in vac. at room temp. for 3h, elem. anal.;100%
aluminium trichloride
7446-70-0

aluminium trichloride

Fe(3+)*4Zr(4+)*18(OCH(CH3)2)(1-)*Cl(1-)

Fe(3+)*4Zr(4+)*18(OCH(CH3)2)(1-)*Cl(1-)

Al(3+)*Fe(3+)*4Zr(4+)*4Cl(1-)*18(OCH(CH3)2)(1-)={AlFeZr4Cl4(OCH(CH3)2)18}

Al(3+)*Fe(3+)*4Zr(4+)*4Cl(1-)*18(OCH(CH3)2)(1-)={AlFeZr4Cl4(OCH(CH3)2)18}

Conditions
ConditionsYield
In benzene mixt. stirred until AlCl3 completely dissolved (ca 10h); evapn. under reduced pressure at room temp., dried (50°C, 0.4 mm, 3h);100%
aluminium trichloride
7446-70-0

aluminium trichloride

Al(3+)*Fe(3+)*2Zr(4+)*13(OCH(CH3)2)(1-)*Cl(1-)

Al(3+)*Fe(3+)*2Zr(4+)*13(OCH(CH3)2)(1-)*Cl(1-)

2Al(3+)*Fe(3+)*2Zr(4+)*4Cl(1-)*13(OCH(CH3)2)(1-)={Al2FeZr2Cl4(OCH(CH3)2)13}

2Al(3+)*Fe(3+)*2Zr(4+)*4Cl(1-)*13(OCH(CH3)2)(1-)={Al2FeZr2Cl4(OCH(CH3)2)13}

Conditions
ConditionsYield
In benzene mixt. stirred until AlCl3 completely dissolved (ca 10h); evapn. under reduced pressure at room temp., dried (50°C, 0.4 mm, 3h); elem. anal.;100%
aluminium trichloride
7446-70-0

aluminium trichloride

(η5-C5H4Me)2TiCl

(η5-C5H4Me)2TiCl

(MeCp)2Ti(AlCl4)

(MeCp)2Ti(AlCl4)

Conditions
ConditionsYield
In benzene100%
aluminium trichloride
7446-70-0

aluminium trichloride

[(η5-pentamethylcyclopentadienyl)2TiCl]

[(η5-pentamethylcyclopentadienyl)2TiCl]

(M5Cp)2Ti(AlCl4)

(M5Cp)2Ti(AlCl4)

Conditions
ConditionsYield
In benzene100%
aluminium trichloride
7446-70-0

aluminium trichloride

methylthiol
74-93-1

methylthiol

(aluminium trichloride)methanethiol
98772-96-4

(aluminium trichloride)methanethiol

Conditions
ConditionsYield
In benzene under N2, CH3SH introduced in a suspension of AlCl3 for 5 min, dissoln.of AlCl3, stirred for 15 min at room temp.; evapn. of solvent, dried in vac. at room temp. for 3h, elem. anal.;100%
aluminium trichloride
7446-70-0

aluminium trichloride

Trimethyl(methylthio)silane
3908-55-2

Trimethyl(methylthio)silane

aluminium trichloride*trimethylsilyl methyl sulphide
112908-11-9

aluminium trichloride*trimethylsilyl methyl sulphide

Conditions
ConditionsYield
In benzene a benzene soln. of Me3SiSMe was added dropwise under N2 to a suspn. of AlCl3 in benzene, mixt. was stirred for 15 min at room temp.; solvent was evapd.; elem. anal.;100%
aluminium trichloride
7446-70-0

aluminium trichloride

(ethylthio)trimethylsilane
5573-62-6

(ethylthio)trimethylsilane

aluminium trichloride*trimethylsilyl ethyl sulphide
112908-12-0

aluminium trichloride*trimethylsilyl ethyl sulphide

Conditions
ConditionsYield
In benzene a benzene soln. of Me3SiSEt was added dropwise under N2 to a suspn. of AlCl3 in benzene, mixt. was stirred for 15 min at room temp.; solvent was evapd.; elem. anal.;100%
aluminium trichloride
7446-70-0

aluminium trichloride

phenylthiotrimethylsilane
4551-15-9

phenylthiotrimethylsilane

aluminium trichloride*trimethylsilyl phenyl sulphide
112908-13-1

aluminium trichloride*trimethylsilyl phenyl sulphide

Conditions
ConditionsYield
In benzene a benzene soln. of Me3SiSPh was added dropwise under N2 to a suspn. of AlCl3 in benzene, mixt. was stirred for 15 min at room temp.; solvent was evapd.; elem. anal.;100%
aluminium trichloride
7446-70-0

aluminium trichloride

methyl methylphenylphosphinate
6389-79-3

methyl methylphenylphosphinate

poly(aluminum methylphenylphosphinate)

poly(aluminum methylphenylphosphinate)

Conditions
ConditionsYield
In further solvent(s) byproducts: MeCl; slow heating in neat Ph(Me)P(O)OMe until complete pptn.; particle size and polymerization degree depending on heating rate;100%
aluminium trichloride
7446-70-0

aluminium trichloride

1-butyl-3-methylimidazolium chloride
79917-90-1

1-butyl-3-methylimidazolium chloride

1-butyl-3-methylimidazolium heptachlorodialuminate

1-butyl-3-methylimidazolium heptachlorodialuminate

Conditions
ConditionsYield
In neat (no solvent) 1-butyl-3-methylimidazolium chloride was mixed with AlCl3 under N2 for 5min.;100%
E.J. Angueira, M.G. White, J. Mol. Catal. A Chem. 227 (1-2) (2005) 51-58; 238 (2005) 163-174;
aluminium trichloride
7446-70-0

aluminium trichloride

triethyl(trimethylsilylimino)phosphorane
13892-04-1

triethyl(trimethylsilylimino)phosphorane

[AlCl2(NP(C2H5)3)]2

[AlCl2(NP(C2H5)3)]2

Conditions
ConditionsYield
In acetonitrile byproducts: Me3SiCl; Ar atm.; equivalent amts., refluxing; evapn. (vac., to dryness); elem. anal.;100%
aluminium trichloride
7446-70-0

aluminium trichloride

syn-Li2[N(SiMe2CH2P(Ph)CH2SiMe2)2N](1,4-dioxane)

syn-Li2[N(SiMe2CH2P(Ph)CH2SiMe2)2N](1,4-dioxane)

syn-AlCl[PhP(CH2SiMe2NSiMe2CH2)2PPh]
219594-43-1, 219594-45-3

syn-AlCl[PhP(CH2SiMe2NSiMe2CH2)2PPh]

Conditions
ConditionsYield
In toluene byproducts: LiCl; inert atmosphere; stirring for 12 h; filtration off of LiCl (Celite), solvent removal (vac.), recrystn. (PhMe, slow evapn.);100%
[N-(2-diphenylphosphinophenyl)-2,6-dimethylanilide]Li(THF)2
678172-48-0

[N-(2-diphenylphosphinophenyl)-2,6-dimethylanilide]Li(THF)2

aluminium trichloride
7446-70-0

aluminium trichloride

[N-(2-diphenylphosphinophenyl)-2,6-dimethylanilide]AlCl2
678172-45-7

[N-(2-diphenylphosphinophenyl)-2,6-dimethylanilide]AlCl2

Conditions
ConditionsYield
In toluene under N2 atm. AlCl3 was added at -35°C to soln. (N-(2-phenylphosphinophenyl)-2,6-dimethylanilide)Li(THF)2 in toluene and stirred at room temp. for 4 days; react. mixt. was filtered, solvent was stripped;100%
aluminium trichloride
7446-70-0

aluminium trichloride

triethylboroxine
3043-60-5

triethylboroxine

A

2,2,8,8,13-pentachloro-4,6,10,12-tetraethyl-1,3,5,7,9,11-hexaoxa-4,6,10,12-tetrabora-2,8,13-trialuminatetracyclo{7.3.1.0(3,13)0(7,13)}tridecane

2,2,8,8,13-pentachloro-4,6,10,12-tetraethyl-1,3,5,7,9,11-hexaoxa-4,6,10,12-tetrabora-2,8,13-trialuminatetracyclo{7.3.1.0(3,13)0(7,13)}tridecane

B

ethyl-dichloro-borane
1739-53-3

ethyl-dichloro-borane

Conditions
ConditionsYield
In neat (no solvent) the educts were warmed with stirring to 40°C, cooled to 20°C;; distn. in vac. (removal of excess boroxine and by-products), residue sublimed in high vac. at about 130 °C; elem. anal.;;A 99.9%
B n/a
aluminium trichloride
7446-70-0

aluminium trichloride

trans-1,2-bis[(trimethylsilyl)oxy]cyclohexane
13871-93-7, 39789-20-3, 39789-21-4, 125329-92-2

trans-1,2-bis[(trimethylsilyl)oxy]cyclohexane

{C6H10(O)(OSi(CH3)3)}2{AlCl2}2
135366-85-7

{C6H10(O)(OSi(CH3)3)}2{AlCl2}2

Conditions
ConditionsYield
In dichloromethane a stirred suspn. of AlCl3 in CH2Cl2 at -78°C was treated dropwise under dry Ar with a soln. of the ether in CH2Cl2, the mixture was kept at 25°C for 20 h; removal of the volatiles by evapn. in vacuo;99.2%
aluminium trichloride
7446-70-0

aluminium trichloride

trimethylaluminum
75-24-1

trimethylaluminum

Conditions
ConditionsYield
With methylmagnesium bromide In not given react. of AlCl3 with MeMgBr;99%
aluminium trichloride
7446-70-0

aluminium trichloride

chlorine
7782-50-5

chlorine

Conditions
ConditionsYield
697°C,in N2;99%
697°C,in N2;99%
With oxygen glowing in O2-stream;
aluminium trichloride
7446-70-0

aluminium trichloride

bis(triphenylphosphine)iminium chloride
21050-13-5

bis(triphenylphosphine)iminium chloride

N(P(C6H5)3)2(1+)*AlCl4(1-)=N(P(C6H5)3)2[AlCl4]
174422-38-9

N(P(C6H5)3)2(1+)*AlCl4(1-)=N(P(C6H5)3)2[AlCl4]

Conditions
ConditionsYield
In tetrahydrofuran inert atmosphere; stirring equimolar amts. (room temp., 4 h); solvent removal (vac.); elem. anal.;99%
praseodymium

praseodymium

aluminium trichloride
7446-70-0

aluminium trichloride

acetonitrile
75-05-8

acetonitrile

Pr(NCCH3)9(3+)*3AlCl4(1-)*CH3CN = [Pr(NCCH3)9](AlCl4)3*CH3CN

Pr(NCCH3)9(3+)*3AlCl4(1-)*CH3CN = [Pr(NCCH3)9](AlCl4)3*CH3CN

Conditions
ConditionsYield
With C2Cl6 In acetonitrile Sonication; (N2); addn. of MeCN to Pr, AlCl3 and C2Cl6, sonication for 3 h; solvent removal (vac.); elem. anal.;99%
aluminium trichloride
7446-70-0

aluminium trichloride

potassium hydridotris(3,5-dimethylpyrazolyl)borate
17567-17-8

potassium hydridotris(3,5-dimethylpyrazolyl)borate

{(tris(3,5-dimethyl-1-pyrazolyl)hydridoborate)2Al}(AlCl4)
112439-53-9

{(tris(3,5-dimethyl-1-pyrazolyl)hydridoborate)2Al}(AlCl4)

Conditions
ConditionsYield
In dichloromethane stirring (18 h, room temp.), solvent removal (vacuum); extraction (CH2Cl2), recrystn. (MeCN);99%
lithium borohydride

lithium borohydride

aluminium trichloride
7446-70-0

aluminium trichloride

aluminum(III) borohydride

aluminum(III) borohydride

Conditions
ConditionsYield
In toluene byproducts: LiCl; treatment of LiBH4 with AlCl3 in toluene; pptn.; distn.;99%
freezing-thawing (vac., 20 to -78°C);
hydrogenchloride
7647-01-0

hydrogenchloride

aluminium trichloride
7446-70-0

aluminium trichloride

(P((CH3)2C6H5))3Cl2Re(N-pyrrolyl)
227932-83-4

(P((CH3)2C6H5))3Cl2Re(N-pyrrolyl)

mer-trichlorotris(dimethylphenylphosphine)rhenium(III)
14710-16-8, 15613-32-8, 24627-46-1

mer-trichlorotris(dimethylphenylphosphine)rhenium(III)

Conditions
ConditionsYield
99%
hydrogenchloride
7647-01-0

hydrogenchloride

aluminium trichloride
7446-70-0

aluminium trichloride

mer-(PMe2Ph)3Cl2Re(3,4-NC4H2Me2)
227932-89-0

mer-(PMe2Ph)3Cl2Re(3,4-NC4H2Me2)

mer-trichlorotris(dimethylphenylphosphine)rhenium(III)
14710-16-8, 15613-32-8, 24627-46-1

mer-trichlorotris(dimethylphenylphosphine)rhenium(III)

Conditions
ConditionsYield
In chloroform-d1 N2-atmosphere; excess of HCl, 1 equiv. of AlCl3, standing for 1-2 days; not sepd.; NMR-spectroscopy;99%
hydrogenchloride
7647-01-0

hydrogenchloride

aluminium trichloride
7446-70-0

aluminium trichloride

mer-(PMe2Ph)3Cl2Re(3-NC4H3Me)*H2O

mer-(PMe2Ph)3Cl2Re(3-NC4H3Me)*H2O

mer-trichlorotris(dimethylphenylphosphine)rhenium(III)
14710-16-8, 15613-32-8, 24627-46-1

mer-trichlorotris(dimethylphenylphosphine)rhenium(III)

Conditions
ConditionsYield
99%
aluminium trichloride
7446-70-0

aluminium trichloride

1-[(1-chloro-1-methylethyl)azo]-2,4,6-trichlorobenzene
32974-66-6

1-[(1-chloro-1-methylethyl)azo]-2,4,6-trichlorobenzene

1,3-Diphenylcarbodiimide
622-16-2

1,3-Diphenylcarbodiimide

4,5-dihydro-4-isopropyl-5(isopropylimino)-2,3-dimethyl-4-phenyl-5-(phenylimino)-1-(2,4,6-trichlorophenyl)-1H-1,2,4-triazolinium tetrachloroaluminate

4,5-dihydro-4-isopropyl-5(isopropylimino)-2,3-dimethyl-4-phenyl-5-(phenylimino)-1-(2,4,6-trichlorophenyl)-1H-1,2,4-triazolinium tetrachloroaluminate

Conditions
ConditionsYield
In dichloromethane inert atmosphere; soln. of N-compounds added dropwise to suspension of AlCl3 at -60°C; stirred for 1 h at -60°C, then for 1 h at 0°C;; evapd.; pptd. from CH2Cl2/pentane; elem. anal.;;99%
aluminium trichloride
7446-70-0

aluminium trichloride

W(O)(CHC(CH3)3)Cl2(P(C2H5)3)2
74666-77-6

W(O)(CHC(CH3)3)Cl2(P(C2H5)3)2

[W(O)(CHC(CH3)3)(P(C2H5)3)2](2+)*2AlCl4(1-)=[W(O)(CHC(CH3)3)(P(C2H5)3)2](AlCl4)2
79357-54-3

[W(O)(CHC(CH3)3)(P(C2H5)3)2](2+)*2AlCl4(1-)=[W(O)(CHC(CH3)3)(P(C2H5)3)2](AlCl4)2

Conditions
ConditionsYield
In dichloromethane AlCl3 was added to stirred soln. of W compd. in CH2Cl2 in ca. 2:1 molarratio; filtered, vol. of filtrate halved in vac., equal vol. of pentane was added, crystd., elem. anal.;99%
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