109155-94-4Relevant academic research and scientific papers
Olefination of carbonyl compounds through reductive coupling of alkenylboronic acids and tosylhydrazones
Perez-Aguilar, M. Carmen,Valdes, Carlos
supporting information; scheme or table, p. 5953 - 5957 (2012/07/30)
The partners decide: The C-C bond-forming reductive cross-coupling of alkenylboronic acids and tosylhydrazones takes place under mild reaction conditions without the need of a metal catalyst, thus giving rise to olefination-type products (see scheme). The position of the double bond in the product is determined by the structure of the coupling partners. Copyright
Modern Friedel-Crafts chemistry. XVI. Sterically controlled cyclodehydration of selected arylalkanols
Khawaga, A. M. El-,Zohry, M. F. El-,Wahab, A. A. Abdel-,Khalaf, A. A.
, p. 1051 - 1055 (2007/10/02)
The cyclodehydration of three selected arylalkanols, namely 1,3-diphenyl-3-pentanol (I), 1,1,4-triphenyl-2methyl-1-butanol (II) and 1,1,4-triphenyl-2-methyl-2-butanol (III) with Friedel-Crafts catalysts was investigated.A reasonable interpretation of the reaction products was suggested, steric hindrance was found to have major influence on the course of the reaction.
