1092078-35-7Relevant articles and documents
An ion-pair template for rotaxane formation and its exploitation in an orthogonal interaction anion-switchable molecular shuttle
Barrell, Michael J.,Leigh, David A.,Lusby, Paul J.,Slawin, Alexandra M. Z.
supporting information; experimental part, p. 8036 - 8039 (2009/04/13)
(Chemical Equation Presented) Chloride control: The serendipitous discovery of a molecular recognition motif that is triggered by the formation of an anion-palladium coordination bond is exploited as an efficient rotaxane-forming template and as the basis of a molecular shuttle. The macrocycle of this rotaxane moves between the two stations when the counterion is changed from chloride to hexafluorophosphate (see picture).
