143998-20-3Relevant articles and documents
Goldberg Active Template Synthesis of a [2]Rotaxane Ligand for Asymmetric Transition-Metal Catalysis
Hoekman, Steven,Kitching, Matthew O.,Leigh, David A.,Papmeyer, Marcus,Roke, Diederik
, p. 7656 - 7659 (2015)
We report on the active template synthesis of a [2]rotaxane through a Goldberg copper-catalyzed C-N bond forming reaction. A C2-symmetric cyclohexyldiamine macrocycle directs the assembly of the rotaxane, which can subsequently serve as a ligan
Self-assembly, spectroscopic, and electrochemical properties of [n]rotaxanes
Ashton,Ballardini,Balzani,Belohradsky,Gandolfi,Philp,Prodi,Raymo,Reddington,Spencer,Stoddart,Venturi,Williams
, p. 4931 - 4951 (2007/10/03)
Synthetic approaches to self-assembling [n]rotaxanes incorporating Π- electron deficient bipyridinium-based dumbbell-shaped components and Π- electron rich hydroquinone-based macrocycles have been developed. In particular, the so-called slippage methodolo
A New Design Strategy for the Self-assembly of Molecular Shuttles
Ashton, Peter R.,Philp, Douglas,Spencer, Neil,Stoddart, J. Fraser
, p. 1124 - 1128 (2007/10/02)
A strategy for the construction of a rotaxane-comprised of a dumbbell-shaped component containing two ?-electron-deficient 4,4'-bipyridinium units encircled by one ?-electron-rich bisparaphenylene-34-crown-10 macrocycle-by a constitutionally determined