1092080-75-5Relevant articles and documents
The use of a single derivative in the configurational assignment of ketone cyanohydrins
Louzao, Iria,Seco, Jose M.,Quinoa, Emilio,Riguera, Ricardo
experimental part, p. 6520 - 6524 (2011/02/22)
The absolute stereochemistry of ketone cyanohydrins can be easily determined by preparing a single MPA derivative. The comparison of two NMR spectra at different temperatures allows the assignment by just paying attention to the evolution of the cyanohydr
Absolute configuration of ketone cyanohydrins by 1H nmr: The special case of polar substituted tertiary alcohols
Louzao, Iria,Garcia, Rosa,Seco, Jose Manuel,Quinoa, Emilio,Riguera, Ricardo
supporting information; experimental part, p. 53 - 56 (2009/07/04)
The absolute configuration of ketone cyanohydrins can be assigned from analysis of the 1H NMR spectra of the corresponding (R)-and (S)-MPA ester derivatives and use of ΔδRS signs. This is an application of the NMR methodology for ste