109240-96-2Relevant academic research and scientific papers
THE SYNTHESIS OF SPIROCYCLIC COMPOUNDS BY REGIOSPECIFIC PALLADIUM CATALYSED CYCLISATION REACTIONS
Grigg, Ronald,Sridharan, Visuvanathar,Stevenson, Paul,Sukirthalingam, Sukanthini
, p. 3557 - 3568 (2007/10/02)
Enamides derived from o-iodobenzoic acid and Z-3-bromoacrylic acid undergo regiospecific palladium catalysed exo-trig cyclisation onto a proximate alkene to give spirocyclic products in good to excellent yield.Double bond isomerisation in the product is n
Palladium(II) Catalysed Construction of Tetrasubstituted Carbon Centres, and Spiro- and Bridged-ring Compounds from Enamides of 2-Iodobenzoic Acids
Grigg, Ronald,Sridharan, Visuvanathar,Stevenson, Paul,Worakun, Tanachat
, p. 1697 - 1699 (2007/10/02)
Various N-vinyl- and N-allyl-amides of 2-iodobenzoic acid undergo catalytic cyclisation in the presence of tetraethylammonium chloride and a palladium acetate-based catalyst system to generate a range of synthetically useful structural features including
