109263-23-2

Upstream product

• 69739-34-0 t-butyldimethylsiyl triflate 
• 826-56-2 4a-methyl-4,4a,5,6,7,8-hexahydro-3H-naphthalen-2-one 
• 91534-13-3 methyl trans-3-(2'-formyl-1'-methylcyclohexyl)propionate 
• 53912-10-0 trans-1,2,3,4,4a,5,6,8a-octahydro-4a-methyl-7-trimethylsiloxynaphthalene 
• 109263-15-2 methyl trans-3-<2'-(1''-hydroxyprop-2''-enyl)-1'-methylcyclohexyl>propionate 
• 150934-10-4 3-((1R,2S)-2-Formyl-1-methyl-cyclohexyl)-propionic acid 
• 91534-14-4 methyl trans-3-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>propionate 

Downstream Products

• 91534-16-6 trans-5-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>-3-trimethylsilylmethylpent-1-en-3-ol 
• 109263-21-0 trans-4-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>-1-trimethylsilylbutan-2-one 
• 109263-24-3 trans-5-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>pent-1-en-3-one 
• 91534-17-7 trans-2-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1-methyl-1-(3'-methylenepent-4'-enyl)cyclohexane 
• 91534-18-8 trans-2-methyl-2-(3'-methylenepent-4'-enyl)cyclohexyl vinyl ketone 
• 109263-22-1 trans-1-<2'-methyl-2'-(3''-methylenepent-4''-enyl)cyclohexyl>-prop-2-enol 
• 109263-25-4 trans-4-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>-1-trimethylsilylbutan-2-ol 
• 115842-84-7 trans-5-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>-3-(1'''-methyl-1'''-phenylselenoethyl)-2-methylpent-1-en-3-ol 
• 115819-60-8 trans-2-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1-methyl-1-<4'-methyl-3'-(1'''-methylvinyl)pent-3'-enyl>cyclohexane 
• 115842-83-6 trans-5-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>-2-methylpent-1-en-3-one 
• 115819-54-0 trans-1-<2'-methyl-2'-<4''-methyl-3''-(1'''-methylvinyl)pent-3''-enyl>cyclohexyl>prop-2-en-1-one 
• 115819-61-9 trans-1-<2'-methyl-2'-<4''-methyl-3''-(1'''-methylvinyl)pent-3''-enyl>cyclohexyl>prop-2-en-1-ol 
• 109263-18-5 trans-5-<2-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>pent-1-en-3-ol 
• 115819-56-2 trans-5-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>-2-methylpent-1-en-3-ol 

Relevant academic research and scientific papers

Synthesis of the Taxane Ring System using an Intramolecular Diels-Alder Reaction of a 2-Substituted Diene

A synthesis of (1R/S,3R/S,8S/R)-8-methyltricyclopentadec-11-en-2-one, which is the ring system of the taxane natural products and contains 3 chiral centres having the required relative configuration, is described.

A Stereocontrolled Route to the Tricyclo3,8>pentadecane Ring System of Taxane

The synthesis of a tricyclo3,8>pentadecane system which has the same relative stereochemistry about its chiral centres as the taxane natural products is reported.