109272-45-9Relevant academic research and scientific papers
COMPLETE REVERSAL OF REGIOCHEMISTRY IN CYCLIC ACYLPALLADATION. NOVEL SYNTHESIS OF QUINONES.
Negishi, Ei-ichi,Tour, James M.
, p. 4869 - 4872 (1986)
Treatment of o-iodoaryl alkenyl ketones with CO (600 psi) in CH3CN in the presence of 5 mol percent of Pd(dba)2 and 1 equiv of NEt3 can give bicyclic and polycyclic quinones in high yields via acylpalladation in an "endo" mode, which appears to be totally
